54695-19-1Relevant articles and documents
Ni(ii) and Pd(ii) pyridinyloxazolidine-compounds: Synthesis, X-ray characterisation and catalytic activities in the aza-Michael reaction
Ardizzoia, G. Attilio,Brenna, Stefano,Therrien, Bruno
experimental part, p. 783 - 790 (2012/02/05)
The 3-phenyl-2-(pyridin-2-yl)oxazolidine ligand (ppo) was synthesised and its coordination behaviour regarding Ni(ii) and Pd(ii) centres was studied. The reaction with K2PdCl4 affords [Pd(N,N′-ppo)Cl 2] (1), in which ppo b
Diastereoselektive Synthese neuartiger Mannich-Basen mittels Titanderivaten
Seebach, Dieter,Betschart, Claudia,Schiess, Martin
, p. 1593 - 1597 (2007/10/02)
Trichlorotitanium dialkylamino-alkoxides (2; titanates of N,O-hemiacetals) are generated either from the corresponding lithium alkoxides and titanium tetrachloride (Scheme I) or by addition of trichloro-dialkylamino-titanium to aldehydes.The electrophilic