54737-34-7

Basic information

• Product Name: Phenoxy, 4-(dimethylamino)-
• CAS NO: 54737-34-7
• Molecular Formula: C8H10NO
• Molecular Weight: 136.173
• Mol File: 54737-34-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phenoxy, 4-(dimethylamino)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenoxy, 4-(dimethylamino)-(54737-34-7)
• EPA Substance Registry System: Phenoxy, 4-(dimethylamino)-(54737-34-7)

Safety Data

• Hazardous Substances Data: 54737-34-7(Hazardous Substances Data)

Upstream product

• 619-60-3 4-(N,N-dimethylamino)phenol 
• 228270-44-8 caffeic acid radical 
• 100-22-1 N,N,N',N'-Tetramethyl-benzene-1,4-diamine 
• 114707-69-6 4-aminoanilino radical 
• 105868-72-2 trolox c radical 
• 5593-75-9 2-Hydroxyphenoxyradikal 
• 126216-42-0 5-Hydroxytryptophan radical 
• 80792-63-8 5-Hydroxyindole radical 
• 3225-30-7 hydroquinone radical 
• 24856-47-1 3-hydroxy-phenyloxyl 
• 6119-34-2 p-aminophenoxyl radical 
• 32942-70-4 7-Hydroxycumarin-Radikal 
• 137475-52-6 perfluorobutylperoxyl radical 
• 69884-58-8 trichloromethyl peroxyl 

Downstream Products

• 619-60-3 4-(N,N-dimethylamino)phenol 
• 32942-70-4 7-Hydroxycumarin-Radikal 
• 105868-72-2 trolox c radical 
• 24856-47-1 3-hydroxy-phenyloxyl 
• 126216-42-0 5-Hydroxytryptophan radical 
• 114707-69-6 4-aminoanilino radical 
• 3225-30-7 hydroquinone radical 
• 5593-75-9 2-Hydroxyphenoxyradikal 
• 6119-34-2 p-aminophenoxyl radical 
• 228270-44-8 caffeic acid radical 
• 100-22-1 N,N,N',N'-Tetramethyl-benzene-1,4-diamine 
• 80792-63-8 5-Hydroxyindole radical 

Relevant articles and documents

Free electron transfer from several phenols to radical cations of non-polar solvents

Electron-transfer reactions from phenols to parent radical cations of solvents were studied using pulse radiolysis. Phenols bearing electron-withdrawing, electron-donating and bulky substituents were investigated in non-polar solvents such as cyclohexane, n-dodecane, n-butyl chloride and 1,2-dichloroethane. The experiments revealed the direct, synchronous formation of phenoxyl radicals and phenol radical cations in all cases and in nearly the same relative amounts. This was explained by two competing electron-transfer channels which depend on the geometry of encounter between the parent solvent radical cations and the solute phenol molecules. The mechanism is analysed at a microscopic level, treating diffusion as a slow process and the local electron transfer as an extremely rapid event. Furthermore, the effect of various phenol substituents and solvent types on the electron-transfer mechanism and on the decay kinetics of the solute phenol radical cations was analysed. The results were further substantiated using a quantum chemical approach.

One-Electron Redox Potentials of Phenols. Hydroxy- and Aminophenols and Related Compounds of Biological Interest

The rate constants for reversible electron transfer between a series of substituted phenolate ions and anilines and various substituted phenoxyl or anilino radicals in aqueous solution were measured by observing the formation or depletion of the radicals involved.Nonequilibrium concentrations of the radicals were produced in the presence of the corresponding phenols or anilines by using the pulse radiolysis technique.The relaxation of the system to equilibrium was monitored by optical detection methods.From the equilibrium constants for one-electron transfer, the one-electron redox potentials (E2) for 38 phenolic or anilino type compounds were determined, many of which are natural products.The redox potentials are strongly influenced by electron-donating or -withdrawing substituents at the aromatic system.