54826-51-6

Basic information

• Product Name: Benzenemethanol, a-(iodomethyl)-, acetate
• CAS NO: 54826-51-6
• Molecular Formula: C10H11IO2
• Molecular Weight: 290.101
• Mol File: 54826-51-6.mol
• Article Data: 23

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(iodomethyl)-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(iodomethyl)-, acetate(54826-51-6)
• EPA Substance Registry System: Benzenemethanol, a-(iodomethyl)-, acetate(54826-51-6)

Safety Data

• Hazardous Substances Data: 54826-51-6(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 70-55-3 toluene-4-sulfonamide 
• 64-19-7 acetic acid 
• 6540-76-7 iodine monoacetate 
• 127-19-5 N,N-dimethyl acetamide 
• 543-90-8 cadmium(II) acetate 
• 108-24-7 acetic anhydride 
• 301-04-2 lead acetate 
• 127-08-2 potassium acetate 
• 1600-27-7 mercury(II) diacetate 
• 563-68-8 thallium(I) acetate 

Downstream Products

• 93-92-5 1-phenylethyl acetate 
• 37464-84-9 methyl 5-acetoxy-5-phenylpentanoate 

Relevant articles and documents

Dihalogenation of Alkenes Using Combinations of N-Halosuccinimides and Alkali Metal Halides

A simple, efficient and eco-friendly method for the vicinal dihalogenation of alkenes is described. The reaction is performed with a combination of a N-halosuccinimide and an alkali metal halide using environmentally benign solvents such as acetic acid an

Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes

A novel and inexpensive, environmentally friendly method for the preparation of iodine monoacetate is presented using iodine and Oxone in acetic acid/acetic anhydride. The reagent is used in a highly efficient approach for the regio- and diastereoselective iodo-acetoxylation of alkenes and alkynes in a simple one-pot process.

Regioselective vicinal functionalization of unactivated alkenes with sulfonium iodate(i) reagents under metal-free conditions

Metal-free, molecular iodine-free direct 1,2-difunctionalization of unactivated alkenes has been reported. The sulfonium iodate(i) reagent efficiently promoted the intermolecular vicinal iodo-functionalization of a diverse range of olefins in a stereo and regioselective manner. This method enables the divergent and straightforward preparation of synthetically useful functionalities; β-iodocarboxylates, β-iodohydrins, and β-iodoethers in a one-step process. Further interconversion of iodo-functionalized derivatives allows easy access to valuable synthetic intermediates en route to biologically active molecules.