54939-04-7Relevant articles and documents
Coe et al.
, p. 19,20, 22 (1975)
Functionalization of saturated fluorocarbons
Stoyanov, Nikolay S.,Ramchandani, Nita,Lemal, David M.
, p. 6549 - 6552 (2007/10/03)
A method is described for transforming perfluoroalkanes and perfluorocycloalkanes bearing tertiary fluorine into perfluoroenolates, which can be variously derivatized.
POLYFLUOROBICYCLO 4,4,0 DECANES. PART II. THE FLUORINATION OF TETRALIN BY POTASSIUM TETRAFLUOROCOBALTATE(III)
Coe, Paul L.,Hu, Chang-Ming,Tatlow, John Colin
, p. 35 - 44 (2007/10/02)
Fluorination of tetralin, using potassium tetrafluorocobaltate(III) at 275-300 deg C, gave a series of compounds with bicyclodecane skeletons, as follows: -hexadecafluoro-1(6)-ene (1); tetradecafluoro-1(6),3(4)-diene (2); 3H-pentadecafluoro-1(6)-ene (3); perfluorotetraline (6) (all reported earlier); 8H-tridecafluoro-1(6),3(4)-diene (4); 3H,4H-tetradecafluoro-1(6)-ene (5); a mixture of 3H,8H- and 3H,9H-tetradecafluoro-1(6)-ene (7 and 8); 2H-undecafluorotetralin (9); 3H,4H,8H-tridecafluoro-1(6)-ene (10).The structures of all the new products (4,5,7-10) were determined by elemental analysis, protone and fluorine nmr, and mass spectrometry.Obviously, with this reagent, the residual 1(6) double bond and the β-hydrogens are the most difficult to replace.
