549504-21-4Relevant articles and documents
An expedient route to p-tert-butylthiacalix[4]arene 1,3-diethers via Mitsunobu reactions
Bitter, István,Csokai, Viktor
, p. 2261 - 2265 (2003)
Regioselective distal dialkylation of p-tert-butylthiacalix[4]arene with alcohols was performed under the Mitsunobu protocol using the DEAD/TPP system. The method provides a versatile tool for obtaining 1,3-diethers with different functional groups in the alkyl chains.
An Unprecedented Photochemical Reaction for Anthracene-Containing Derivatives
Zhao, Jiang-Lin,Jiang, Xue-Kai,Wu, Chong,Wang, Chuan-Zeng,Zeng, Xi,Redshaw, Carl,Yamato, Takehiko
, p. 3217 - 3222 (2016/10/25)
A series of anthracene-containing derivatives have been synthesised and characterised. The photochemical behaviour of these derivatives have been investigated by 1H NMR spectroscopy. An unprecedented photolysis reaction for anthracene-containing derivatives was observed in the case of anthracenes directly armed with a -CH2O-R group upon UV irradiation. The photolysis reaction process has been demonstrated to occur in three steps. Firstly, the anthracene-containing derivatives are converted into the corresponding endoperoxide intermediate upon UV irradiation in the presence of air; then, the endoperoxide intermediate is decomposed to the corresponding starting compound and 9-anthraldehyde; finally, 9-anthraldehyde is further oxidised to anthraquinone. Additionally, the photolysis reaction of anthracene-containing derivatives is significantly promoted in the presence of a thiacalix[4]arene platform.
Synthesis, crystal structure and complexation behaviour of a thiacalix[4]arene bearing 1,2,3-triazole groups
Ni, Xin-Long,Zeng, Xi,Hughes, David L.,Redshaw, Carl,Yamato, Takehiko
body text, p. 689 - 695 (2012/03/11)
The structure and complexation behaviour of 1,3-alternate-1,2,3-triazole based on thiacalix[4]arene,1,3-alternate-1 and 2 have been determined by means of X-ray analysis, fluorescence and 1H NMR spectroscopy. The X-ray results suggested that th
