55064-56-7Relevant articles and documents
Formal Semisynthesis of Demethylgorgosterol Utilizing a Stereoselective Intermolecular Cyclopropanation Reaction
Rosenbaum, Nicolai,Schmidt, Lisa,Mohr, Florian,Fuhr, Olaf,Nieger, Martin,Br?se, Stefan
, p. 1568 - 1574 (2021/02/26)
In this study, we report a convenient and high yielding formal semisynthesis of demethylgorgosterol, a marine steroid with an intriguing sidechain containing a cyclopropane unit. This was achieved through the synthesis of an advanced ketone intermediate.