55153-67-8

Basic information

• Product Name: triphenylphosphine ditriflate
• Synonyms: triphenylphosphine ditriflate
• CAS NO: 55153-67-8
• Molecular Weight: 560.432
• Mol File: 55153-67-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: triphenylphosphine ditriflate(CAS DataBase Reference)
• NIST Chemistry Reference: triphenylphosphine ditriflate(55153-67-8)
• EPA Substance Registry System: triphenylphosphine ditriflate(55153-67-8)

Safety Data

• Hazardous Substances Data: 55153-67-8(Hazardous Substances Data)

Upstream product

• 125672-05-1 phenyl[(trifluoromethane)sulfonyloxy]-lambda-3-iodanyl trifluoromethanesulfonate 
• 603-35-0 triphenylphosphine 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 791-28-6 Triphenylphosphine oxide 

Relevant articles and documents

Simple formylation of aromatic compounds using a sodium formate/triphenylphosphine ditriflate system

A new procedure was developed for formylation of arenes to produce aromatic aldehydes using a sodium formate/triphenylphosphine ditriflate system in ethanol at room temperature in good yields. The simplicity of the procedure, short reaction times, and mild reaction conditions are the other advantages of this metal- and carbon monoxide-free protocol.

Synthesis of diarylmethanes via a Friedel-Crafts benzylation using arenes and benzyl alcohols in the presence of triphenylphosphine ditriflate

Triphenylphosphine ditriflate (TPPD) was found to be an efficient promoter for the Friedel-Crafts benzylation of arenes with benzyl alcohols in CH 2Cl2 at room temperature. The good yields, the 1:1 molar ratio of arene and benzyl alcohol, the benzylation of chlorobenzene as a nonactivated aromatic compound at room temperature, and no by-product formation are the main advantages of this procedure.