5516-85-8Relevant articles and documents
Enantioselective Synthesis of Pyrroloindolines via Noncovalent Stabilization of Indole Radical Cations and Applications to the Synthesis of Alkaloid Natural Products
Gentry, Emily C.,Rono, Lydia J.,Hale, Martina E.,Matsuura, Rei,Knowles, Robert R.
supporting information, p. 3394 - 3402 (2018/03/13)
While interest in the synthetic chemistry of radical cations continues to grow, controlling enantioselectivity in the reactions of these intermediates remains a challenge. Based on recent insights into the oxidation of tryptophan in enzymatic systems, we
Enantioselective synthesis of (-)-idiospermuline
Overman, Larry E.,Peterson, Emily A.
, p. 6905 - 6919 (2007/10/03)
The enantioselective total synthesis of the nonacyclic polypyrrolidinoindoline (-)-idiospermuline is described. Stereocontrolled formation of the vicinal quaternary carbon centers is achieved in a single step by dialkylation of an unsymmetrical prostereog