55164-19-7Relevant articles and documents
Chloride-tolerant gold(I)-catalyzed regioselective hydrochlorination of alkynes
Ebule, Rene,Liang, Shengzong,Hammond, Gerald B.,Xu, Bo
, p. 6798 - 6801 (2017/11/09)
We have developed a highly regioselective homogeneous gold(I)-catalyzed anti-hydrochlorination of unactivated alkynes at room temperature. We have overcome the incompatibility between conventional cationic gold catalysts and chloride by using a hydrogen-b
Stereochemistry of the Reactions of CuI Catalyzed Grignard Reagents with Ethyl (E)- and (Z)-β-Chlorocinnamates
Jalander, Lars,Broms, Merete
, p. 173 - 178 (2007/10/02)
Ethyl (E)- and (Z)-3-chloro-3-phenyl-2-propenoate were prepared and separated.The (Z)-isomer gave β-alkylated ethyl cinnamates in good yield when reacted with alkyl Grignard reagents in the presence of 10percent CuI.The (Z)-isomer reacted with retention o