552333-50-3

Basic information

• Product Name: Benzene, 1-(2-methylpropyl)-2,4-dinitro-
• CAS NO: 552333-50-3
• Molecular Formula: C10H12N2O4
• Molecular Weight: 224.216
• Mol File: 552333-50-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(2-methylpropyl)-2,4-dinitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(2-methylpropyl)-2,4-dinitro-(552333-50-3)
• EPA Substance Registry System: Benzene, 1-(2-methylpropyl)-2,4-dinitro-(552333-50-3)

Safety Data

• Hazardous Substances Data: 552333-50-3(Hazardous Substances Data)

Upstream product

• 100-86-7 2-Methyl-1-phenyl-2-propanol 
• 538-93-2 1-phenyl-2-methylpropane 
• 97-00-7 1-chloro-2,4-dinitro-benzene 
• 7664-93-9 sulfuric acid 
• 7697-37-2 nitric acid 

Relevant articles and documents

Cross-coupling of aryl halides and triflates with intramolecularly stabilized group 13-metal alkylating reagents in the presence of mixed-metal catalysts

In the presence of tertiary phosphines, the palladium-containing mixed-metal complexes [(CO)4Fe(μ-PPh2)Pd(μ-Cl)]2(1) and [(CO)3Co]2(μ-CO)Pd[μ-(Ph2PCH 2)2] (2) catalyze the cross-coupling of aryl triflates and halides (including chlorides) with intramolecularly stabilized dialkylaluminum, -gallium and -indium reagents 3-8. The reactions are high yielding, and homocoupling and hydrodehalogenation processes are minimal even when the alkyl moieties of the alkylating reagents contain β-hydrogen atoms. As the components of the mixed-metal complexes are either poor catalysts, or completely inactive, the high catalytic activity of 1 and 2 is attributed to synergism between the different metal nuclei of the catalysts.