55322-67-3

Basic information

• Product Name: bis(2,2,2-trifluoroethyl) phenylphosphonite
• CAS NO: 55322-67-3
• Molecular Formula: C₁₀H₉F₆O₂P
• Molecular Weight: 306.1414
• Mol File: 55322-67-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 216.9°C at 760 mmHg
• Flash Point: 85°C
• Vapor Pressure: 0.201mmHg at 25°C
• CAS DataBase Reference: bis(2,2,2-trifluoroethyl) phenylphosphonite(CAS DataBase Reference)
• NIST Chemistry Reference: bis(2,2,2-trifluoroethyl) phenylphosphonite(55322-67-3)
• EPA Substance Registry System: bis(2,2,2-trifluoroethyl) phenylphosphonite(55322-67-3)

Safety Data

• Hazardous Substances Data: 55322-67-3(Hazardous Substances Data)

Upstream product

• 75-89-8 2,2,2-trifluoroethanol 
• 644-97-3 Dichlorophenylphosphine 

Downstream Products

• 122348-13-4 Phenyl-(2,2,2-trichloro-1-hydroxy-ethyl)-phosphinic acid 2,2,2-trifluoro-ethyl ester 
• 63325-06-4 phenyltetrakis(2,2,2-trifluoroethoxy)phosphorane 
• 75-89-8 2,2,2-trifluoroethanol 

Relevant articles and documents

The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds with sulfenate esters

The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds, ArnP(OCH2CF3)3-n with arylsulfenate esters, ArSOCH2CF3, are reported. Product analysis, kinetic order, activation parameters, Hammett data and solvent effects are the criteria used to elucidate the two step mechanism involving arylthiophosphoranes as intermediates.

PHOSPHORANES FORMED FROM THE CONDENSATION OF TRICO-ORDINATE PHOSPHORUS COMPOUNDS WITH PHENANATHRAQUINONE

The synthesis of a range of monocyclic and bicyclic phosphoranes from the condensation of trico-ordinate phosphorus compounds with phenanthraquinone is reported together with their 31P, 1H and 13C nmr data.The phosphorus chemical shifts of these compounds