55360-45-7

Basic information

• Product Name: Benzenemethanol, 3-methoxy-a-(3-methoxyphenyl)-
• Synonyms: di(m-methoxyphenyl)methyl alcohol;bis-(3-methoxy-phenyl)-methanol;3,3'-dimethoxybenzhydrol;3,3'-Dimethoxy-benzhydrol
• CAS NO: 55360-45-7
• Molecular Formula: C15H16O3
• Molecular Weight: 244.29
• Mol File: 55360-45-7.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 210 - 212 °C (6 mmHg)
• Density: 1.135±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzenemethanol, 3-methoxy-a-(3-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 3-methoxy-a-(3-methoxyphenyl)-(55360-45-7)
• EPA Substance Registry System: Benzenemethanol, 3-methoxy-a-(3-methoxyphenyl)-(55360-45-7)

Safety Data

• Hazardous Substances Data: 55360-45-7(Hazardous Substances Data)

Upstream product

• 36282-40-3 (3-methoxyphenyl)magnesium bromide 
• 591-31-1 3-methoxy-benzaldehyde 
• 2398-37-0 3-methoxyphenyl bromide 
• 124-38-9 carbon dioxide 
• 2845-89-8 1-chloro-3-methoxy-benzene 
• 31600-88-1 m-methoxyphenyllithium 
• 109-94-4 formic acid ethyl ester 

Downstream Products

• 1622071-23-1 C₁₇H₁₈O₄ 
• 189567-33-7 di(3-methoxyphenyl)methyl bromide 
• 112895-98-4 6-Methoxy-4-(3-methoxy-phenyl)-1,2,3,4-tetrahydro-isoquinoline 
• 112896-01-2 1-{6-(4-Chloro-butoxy)-4-[3-(4-chloro-butoxy)-phenyl]-3,4-dihydro-1H-isoquinolin-2-yl}-ethanone 
• 112895-99-5 1-[(R)-6-Methoxy-4-(3-methoxy-phenyl)-3,4-dihydro-1H-isoquinolin-2-yl]-ethanone 
• 112896-00-1 1-[(R)-6-Hydroxy-4-(3-hydroxy-phenyl)-3,4-dihydro-1H-isoquinolin-2-yl]-ethanone 
• 112965-88-5 (-)-6-methoxy-4-(3-methoxyphenyl)-1,2,3,4-tetrahydroisoquinoline 
• 112896-01-2 (-)-N-acetyl-6-(4-chlorobutoxy)-4-<3-(4-chlorobutoxy)phenyl>-1,2,3,4-tetrahydroisoquinoline 
• 113260-28-9 bis(3-methoxyphenyl)<(trimethylsily)oxy>acetonitrile 
• 112895-99-5 (-)-N-acetyl-6-methoxy-4-(3-methoxyphenyl)-1,2,3,4-tetrahydroisoquinoline 
• 112896-00-1 (-)-N-acetyl-6-hydroxy-4-(3-hydroxyphenyl)-1,2,3,4-tetrahydroisoquinoline 
• 112895-98-4 6-Methoxy-4-(3-methoxy-phenyl)-1,2,3,4-tetrahydro-isoquinoline 
• 112895-96-2 N-(tert-butyloxycarbonyl)-N-(hydroxymethyl)-2,2-bis(3-methoxyphenyl)ethylamine 
• 112895-97-3 N-(tert-butyloxycarbonyl)-6-methoxy-4-(3-methoxyphenyl)-1,2,3,4-tetrahydroisoquinoline 

Relevant articles and documents

Photo-induced phosphorus radical involved semipinacol rearrangement reaction: Highly synthesis of γ-oxo-phosphonates

Hydroxyphosphoric acids display the unique biological activities, and they have some attractive prospects as clinical drug moleculars. Herein, a new approach for the synthesis of γ-oxo-phosphonates (the precursor of hydroxyphosphoric acid) has been established through the semipinacol rearrangement tactic involved the photo-induced phosphorus radical process. Most important, this transformation is avoid of the external oxidants, and occurs very well under the sunlight irradiation, meanwhile the γ-oxo-phosphonate was easily derivatized to obtain γ-hydroxyphosphoric acid, thus highlights the synthesis value of this method.

CoI-Catalyzed Barbier Reactions of Aromatic Halides with Aromatic Aldehydes and Imines

The reductive Barbier coupling of aromatic halides and electrophiles has been achieved using a CoBr2/1,10-phenanthroline catalytic system and over stoichiometric amounts of zinc. The reaction displayed a broad scope of substrates, including (hetero)aryl chlorides as pro-nucleophiles and aldehydes or imines as electrophiles, leading to diarylmethanols and diarylmethylamines in moderate to excellent yields, respectively.

Visible light-mediated arylalkylation of allylic alcohols through concomitant 1,2-aryl migration

A photocatalytic process for selective arylalkylation of allylic alcohols with α-bromo diethyl malonate has been developed. The reaction provided a straightforward approach to synthesize α-aryl-β-alkylated ketones via unique 1,2-aryl migration. The procedure is highlighted by its operational simplicity and mild reaction conditions.