5537-72-4

Basic information

• Product Name: m-(Phenylthio)benzoic acid
• Synonyms: m-(Phenylthio)benzoic acid
• CAS NO: 5537-72-4
• Molecular Formula: C₁₃H₁₀O₂S
• Molecular Weight: 230.28
• Mol File: 5537-72-4.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 424.8°C at 760 mmHg
• Flash Point: 210.7°C
• Appearance: /
• Density: 1.31g/cm³
• Vapor Pressure: 5.66E-08mmHg at 25°C
• Refractive Index: 1.674
• CAS DataBase Reference: m-(Phenylthio)benzoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: m-(Phenylthio)benzoic acid(5537-72-4)
• EPA Substance Registry System: m-(Phenylthio)benzoic acid(5537-72-4)

Safety Data

• Hazardous Substances Data: 5537-72-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H10O2S/c14-13(15)10-5-4-8-12(9-10)16-11-6-2-1-3-7-11/h1-9H,(H,14,15)

Upstream product

• 952-97-6 4-nitrophenyl phenyl sulfide 
• 585-76-2 m-bromobenzoic acid 
• 1192-40-1 copper(I) thiophenolate 
• 25487-66-5 3-Carboxyphenylboronic acid 
• 108-98-5 thiophenol 
• 591-50-4 iodobenzene 

Downstream Products

• 2548-44-9 3-benzenesulfonyl-benzoic acid 
• 106380-90-9 3-phenylsulfanylbenzamide 
• 114694-98-3 3-phenylsulfanyl-benzoic acid-(4-phenyl-phenacyl ester) 
• 52207-85-9 3-Phenyl-thio-benzoylchlorid 
• 131073-60-4 3-Benzenesulfinyl-benzoic acid 
• 40730-42-5 methyl 3-phenylsulfanylbenzoate 
• 141357-93-9 N,N-dimethyl-3-(phenylthio)benzylamine 
• 73149-81-2 1-Chloromethyl-3-phenylsulfanyl-benzene 
• 73149-92-5 5-phenylsulfanyl-indan-1-one 
• 73149-82-3 Sulfurous acid bis-(3-phenylsulfanyl-benzyl) ester 
• 73149-88-9 3-(3-Phenylsulfanyl-phenyl)-propionic acid 
• 73149-85-6 2-(3-Phenylsulfanyl-benzyl)-malonic acid diethyl ester 

Relevant articles and documents

SINGLE-STEP SYNTHESIS METHOD OF ARYL THIOL AND APPLICATION THEREOF

The present invention relates to a single-step synthesis method of aryl thiol, and more specifically, to a method of synthesizing aryl thiol in a single-step by making aryl halide react with alkane dithiol in the presence of a transition metal catalyst. According to the present invention, a single-step synthesis method using the transition metal catalyst, the synthesis method which is capable of synthesizing aryl thiol from aryl halide at a high yield, can be provided. Various aryl halides may be applied to the synthesis method. Further, the synthesis method has advantages that an easily usable reagent may be used, operations are simple, and reactions can be performed under mild conditions. In addition, the synthesized aryl thiol may be used in the synthesis of advanced molecules such as diaryl sulfides and benzothiophenes.COPYRIGHT KIPO 2017

Chan-lam-type s-arylation of thiols with boronic acids at room temperature

In this work, an efficient CuSO4-catalyzed S-arylation of thiols with aryl and heteroaryl boronic acids at room temperature is established. This catalytic system can tolerate a wide variety of thiols and arylboronic acids in the presence of only 5 mol % of CuSO4 as the catalyst and inexpensive 1,10-phen?H2O as the ligand. Moreover, this catalytic system used environment-friendly solvent (EtOH) and oxidant (oxygen).