5554-24-5

Basic information

• Product Name: 3-METHOXYPHENYLBENZOATE
• Synonyms: 3-METHOXYPHENYLBENZOATE
• CAS NO: 5554-24-5
• Molecular Formula: C₁₄H₁₂O₃
• Molecular Weight: 228.24
• Mol File: 5554-24-5.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 355.3°Cat760mmHg
• Flash Point: 148°C
• Appearance: /
• Density: 1.159g/cm³
• Vapor Pressure: 3.17E-05mmHg at 25°C
• Refractive Index: 1.569
• CAS DataBase Reference: 3-METHOXYPHENYLBENZOATE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-METHOXYPHENYLBENZOATE(5554-24-5)
• EPA Substance Registry System: 3-METHOXYPHENYLBENZOATE(5554-24-5)

Safety Data

• Hazardous Substances Data: 5554-24-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H12O3/c1-16-12-8-5-9-13(10-12)17-14(15)11-6-3-2-4-7-11/h2-10H,1H3

Upstream product

• 150-19-6 O-methylresorcine 
• 98-88-4 benzoyl chloride 
• 65-85-0 benzoic acid 
• 100-52-7 benzaldehyde 
• 100-51-6 benzyl alcohol 
• 10365-98-7 3-methoxyphenylboronic acid 
• 108-86-1 bromobenzene 
• 30114-41-1 3-methoxyphenyl formate 
• 150-78-7 1,4-dimethoxybezene 
• 591-50-4 iodobenzene 
• 201230-82-2 carbon monoxide 
• 58585-84-5 1,3-dioxoisoindolin-2-yl benzoate 
• 766-85-8 3-methoxy-1-iodobenzene 
• 140-29-4 phenylacetonitrile 

Downstream Products

• 138372-91-5 α-(3-methoxyphenoxy)styrene 
• 131-57-7 Benzophenone-3 
• 817-95-8 ethyl 2-ethoxyethanoate 
• 93-89-0 benzoic acid ethyl ester 
• 65-85-0 benzoic acid 
• 141-05-9 Diethyl maleate 

Relevant articles and documents

Copper-mediated simple and direct aerobic oxidative esterification of arylacetonitriles with alcohols/phenols

A simple and direct aerobic oxidative esterification reaction of arylacetonitriles with alcohols/phenols is achieved in the presence of a copper salt and molecular oxygen, which produces a broad range of aryl carboxylic acid esters in good to high yields. Copper salt plays multiple roles in the transformation, which allows the oxygenation of C-H bond, cleavage of inert C-C bond, and formation of C-O bond in one pot without the assistance of any of the acids, bases, ligands, and so on. The reaction provides a simple, direct, and efficient protocol towards functionalized esters, especially aryl benzoates, from readily available starting materials.

Nickel-Catalyzed Cross-Coupling of Aryl Redoxactive Esters with Aryl Zinc Reagents

A nickel-catalyzed aryl-aroyloxyl C(sp2)-O radical cross-coupling reaction conducted using a redox active ester with aryl zinc reagent was developed. This method demonstrates a new disconnection approach for formation of aryl aryl esters. In the one-pot sequential process, the readily available aryl carboxylic acids can be converted into functionalized aryl aryl esters and heteroaryl esters. This protocol is amenable to the gram-scale synthesis. The present method has a wide substrate scope and high functional group tolerance.

Transition-Metal-Free Poly(thiazolium) Iodide/1,8-Diazabicyclo[5.4.0]undec-7-ene/Phenazine-Catalyzed Esterification of Aldehydes with Alcohols

Poly(3,4-dimethyl-5-vinylthiazolium) iodide was used as a polymer precatalyst in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) and phenazine for the oxidative esterification of aldehydes with alcohols. Selective functionalization of OH groups was achieved in the presence of NH2 groups. The poly(thiazolium) iodide/DBU/phenazine system exhibited excellent catalytic activity and could be reused five times without loss of activity.