55559-76-7

Basic information

• Product Name: 1,3-Dioxolane, 4-(2-chloroethyl)-2,2-dimethyl-
• Synonyms: 1-chloro-3,4-O,O-i-propylidenebutane-3,4-diol;4-chloro-1,2-O-isopropylidene-1,2-butanediol
• CAS NO: 55559-76-7
• Molecular Formula: C7H13ClO2
• Molecular Weight: 164.63000
• Mol File: 55559-76-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-Dioxolane, 4-(2-chloroethyl)-2,2-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dioxolane, 4-(2-chloroethyl)-2,2-dimethyl-(55559-76-7)
• EPA Substance Registry System: 1,3-Dioxolane, 4-(2-chloroethyl)-2,2-dimethyl-(55559-76-7)

Safety Data

• Hazardous Substances Data: 55559-76-7(Hazardous Substances Data)

Upstream product

• 5754-34-7 4-(2-hydroxyethyl)-2,2-dimethyl-1,3-dioxolane 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 180038-20-4 3-(2-chloroethyl)-1,4-dioxaspiro[4.5]decane 
• 83968-02-9 2,2-dimethyl-4-vinyl-1,3-dioxolane 

Relevant articles and documents

EFFICIENT AND REGIOCONTROLLED NICKEL(II)-CATALYZED ALKYLATION OF 2-ALKYL-1,3-DIOXEP-4-ENES BY GRIGNARD REAGENTS: A SIMPLE ROUTE TO ALLYLIC ALCOHOLS

The regio- and the stereochemistries of the NidppeCl2 catalyzed alkylation of 2-alkyl-1,3-dioxep-4-enes by Grignard reagents are not affected by the nature of the C2 substituent; in any case, allylic alcohols are the main reaction products and nearly pure Z isomers are almost quantitatively obtained when either secondary or tertiary Grignard reagents are used.A rationale for the reaction is proposed.