55628-56-3Relevant articles and documents
Regio- and Stereoselective Synthesis of 1,2- cis-Glycosides by Anomeric O-Alkylation with Organoboron Catalysis
Izumi, Sanae,Kobayashi, Yusuke,Takemoto, Yoshiji
supporting information, p. 665 - 670 (2019/01/21)
Regio- and stereoselective synthesis of 1,2-cis-glycosides has been achieved by catalytic anomeric O-alkylation using organoboron compounds. Modulating steric and electronic factors of both catalysts and substrates enables activation of the axially oriented anomeric oxygens of glucose-derived dialkoxyborates. The mild reaction conditions allow broad functional-group tolerance. This approach can be applied to the efficient sequential synthesis of oligosaccharides.
Disaccharide-containing macrocycles by click chemistry and intramolecular glycosylation
Tiwari, Vinod K.,Kumar, Amit,Schmidt, Richard R.
, p. 2945 - 2956 (2012/07/27)
In this study o- and m-xylylene moieties in combination with a triazolylmethyl moiety have been successfully employed as a relatively rigid spacer system in intramolecular glycosylation reactions. Phenyl 3,4,6-tri-O-benzyl-2-O-propargyl-1-thio-D-glucopyra
Biotin sulfone tagged oligomannosides as immunogens for eliciting antibodies against specific mannan epitopes
Despras, Guillaume,Robert, Raymond,Sendid, Boualem,MacHez, Emeline,Poulain, Daniel,Mallet, Jean-Maurice
experimental part, p. 1817 - 1831 (2012/05/20)
Biotinylated tri and tetrasaccharide: α Man (1→3) α Man (1→2) α Man; α Man (1→3) α Man (1→2) α Man (1→2) α Man were prepared using methyl tertbutyl phenyl thioglycosides glycosyl donors (MBP) and biotin sulfone strategy. Three key mannosyl thioglycosidic