55674-14-1

Basic information

• Product Name: (Z)-ethyl 2-oxo-4-phenyl-3-butenoate
• Synonyms: (Z)-ethyl 2-oxo-4-phenyl-3-butenoate
• CAS NO: 55674-14-1
• Molecular Weight: 204.225
• Mol File: 55674-14-1.mol
• Article Data: 42

Chemical Properties

• CAS DataBase Reference: (Z)-ethyl 2-oxo-4-phenyl-3-butenoate(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-ethyl 2-oxo-4-phenyl-3-butenoate(55674-14-1)
• EPA Substance Registry System: (Z)-ethyl 2-oxo-4-phenyl-3-butenoate(55674-14-1)

Safety Data

• Hazardous Substances Data: 55674-14-1(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 17451-19-3 benzylidene pyruvic acid 
• 75-03-6 ethyl iodide 
• 924-44-7 glyoxylic acid ethyl ester 
• 536-74-3 phenylacetylene 
• 70-23-5 ethyl Bromopyruvate 
• 13321-61-4 ethyl 2-oxo-3-(triphenylphosphoranylidene)propanoate 
• 100-52-7 benzaldehyde 
• 202396-35-8 2-Benzotriazol-1-yl-4-ethoxy-N-isopropyl-2-phenoxy-4-phenyl-butyramide 
• 126580-12-9 (E)-ethyl 2-diazo-4-phenylbut-3-enoate 
• 20207-18-5 rac-2-hydroxy-4-phenyl-3-butynoic acid ethyl ester 
• 1026704-64-2 ethyl 2-((4-methoxyphenyl)imino)-4-phenylbut-3-ynoate 
• 557-20-0 diethylzinc 
• 105074-39-3 7-Dimethylamino-3-styryl-1,4-benzoxazin-2-one 

Downstream Products

• 1149375-88-1 (4R)-ethyl 2-hydroxy-5-oxo-4-phenyl-3,4,5,6,7,8-hexahydro-2H-chromene-2-carboxylate 
• 1175004-50-8 (S)-ethyl 2-hydroxy-7,7-dimethyl-5-oxo-4-phenyl-3,4,5,6,7,8-hexahydro-2H-chromene-2-carboxylate 
• 1149375-82-5 C₂₀H₂₄O₅ 
• 1253115-25-1 C₂₂H₁₈O₆ 
• 1257520-12-9 (4R,4aS,7aS)-ethyl 4-phenyl-4,4a,5,7a-tetrahydrocyclopenta[b]pyran-2-carboxylate 
• 1201890-20-1 ethyl 2-oxo-2-((2S,3R)-3-phenyloxiran-2-yl)acetate 
• 1313263-58-9 (R,Z)-1-ethoxy-5-nitro-1-oxo-4-phenylpent-2-en-2-yl 2-methoxybenzoate 

Relevant articles and documents

Synthesis of Ketones by C?H Functionalization of Aldehydes with Boronic Acids under Transition-Metal-Free Conditions

A method for the synthesis of ketones from aldehydes and boronic acids via a transition-metal-free C?H functionalization reaction is reported. The method employs nitrosobenzene as a reagent to drive the simultaneous activation of the boronic acid as a boronate and the activation of the C?H bond of the aldehyde as an iminium species that triggers the key C?C bond-forming step via an intramolecular migration from boron to carbon. These findings constitute a practical, scalable, and operationally straightforward method for the synthesis of ketones.

Iodine mediated a simple strategy for the synthesis of β,γ-unsaturated-α-ketoesters and its application for the synthesis of 4,5-dihydropyrazole derivatives

Abstract: Novel and efficient method for the synthesis of a series of β,γ-unsaturated-α-ketoesters under mild conditions was developed. This one-step protocol was achieved by the reaction of electron-rich aromatic aldehydes and pyruvates in the presence o

Direct Synthesis of β,γ-Unsaturated α-Keto Esters from Aldehydes and Pyruvates

Herein, we describe two practical methods to synthesize β,γ-unsaturated α-keto esters directly from aldehydes and pyruvates promoted by BF 3 ?Et 2 O in the presence of Ac 2 O or by Ti(OEt) 4 under mild condition