5577-67-3 Usage
Description
N-TERT-BUTYLTRIMETHYLSILYLAMINE, also known as N-tert-Butyltrimethylsilylamine (Me3SiNH-t-Bu), is an organic compound that is characterized by its reactivity and ability to form various chemical products. It is a versatile reagent in the field of organic synthesis, particularly in the preparation of chalcogenides and the synthesis of N-alkylaminomethylphosphonates.
Uses
Used in Chemical Synthesis:
N-TERT-BUTYLTRIMETHYLSILYLAMINE is used as a reagent for the preparation of selenium and tellurium chalcogenides. It plays a crucial role in the synthesis process due to its ability to react with specific compounds, leading to the formation of these chalcogenides.
Used in Pharmaceutical Industry:
N-TERT-BUTYLTRIMETHYLSILYLAMINE is used as a reagent for the facile synthesis of N-alkylaminomethylphosphonates. These compounds have potential applications in the development of new pharmaceuticals, particularly in the area of medicinal chemistry.
Check Digit Verification of cas no
The CAS Registry Mumber 5577-67-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,5,7 and 7 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 5577-67:
(6*5)+(5*5)+(4*7)+(3*7)+(2*6)+(1*7)=123
123 % 10 = 3
So 5577-67-3 is a valid CAS Registry Number.
InChI:InChI=1/C7H19NSi/c1-7(2,3)8-9(4,5)6/h8H,1-6H3
5577-67-3Relevant articles and documents
Synthesis and Structures of New 1,3,2,4-Diphosphadiboretanes
Koelle, Peter,Linti, Gerald,Noeth, Heinrich,Wood, Gary L.,Narula, Chaitanya K.,Paine, Robert T.
, p. 871 - 880 (2007/10/02)
Three methods have been devised to prepare new diphosphadiboretanes: a) Base-induced hydrogen halide elimination from (amino)phosphinoboron halides precursors, b) tris(trimethylsilyl)phosphane elimination from R2N-B2 intermediates prepared in situ from combination of R2N-B(Cl)-P(SiMe3)2 and LiP(SiMe3)2, and organylphosphane elimination from aminobis(organylphosphino)boranes R2N-B(PHR')2.The molecular structures of three new 1,3,2,4-diphosphadiboretanes (3, 4a, 4c) were determined by X-ray diffractometry.These are characterized by a planar four-membered B2P2 ring with the phosphorus substituents in trans positions.Their BP bomnds represent single bond distances.Experimental results are compared with MNDO III calculations which reveal a low barrier (ΔE = 5 kcal/mol) for the dimerization of the boraphosphane H2N-B=PMe to the diphospadiboretane (H2N-BPMe)2.
Acidity Measurements on Pyridines in Tetrahydrofuran Using Lithiated Silylamines
Fraser, Robert R.,Mansour, Tarek S.,Savard, Sylvain
, p. 3232 - 3234 (2007/10/02)
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