55816-08-5

Basic information

• Product Name: (E)-(4,8-dimethylnona-1,7-dien-1-yl)benzene
• Synonyms: (E)-(4,8-dimethylnona-1,7-dien-1-yl)benzene
• CAS NO: 55816-08-5
• Molecular Weight: 228.378
• Mol File: 55816-08-5.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (E)-(4,8-dimethylnona-1,7-dien-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(4,8-dimethylnona-1,7-dien-1-yl)benzene(55816-08-5)
• EPA Substance Registry System: (E)-(4,8-dimethylnona-1,7-dien-1-yl)benzene(55816-08-5)

Safety Data

• Hazardous Substances Data: 55816-08-5(Hazardous Substances Data)

Upstream product

• 7417-81-4 benzyl phenyl sulfoxide 
• 55816-07-4 citronellyl iodide 
• 4406-72-8 2-phenyl[1,3,2]dioxaborolane 
• 62108-28-5 4,8-dimethylnona-1,7-diene 
• 87802-71-9 (E)-methyl cinnamyl carbonate 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Stereoselective Rhodium-Catalyzed Isomerization of Stereoisomeric Mixtures of Arylalkenes

A new efficient method for the synthesis of a high ratio of E -alkenes from E / Z mixtures of alkenes with B 2pin 2in the presence of a rhodium catalyst is described. This reaction features mild reaction conditions, broad functional group tolerance, and highly great application potential.

Regioselective Single-Electron Tsuji-Trost Reaction of Allylic Alcohols: A Photoredox/Nickel Dual Catalytic Approach

A radical-mediated functionalization of allyl alcohol derived partners with a variety of alkyl 1,4-dihydropyridines via photoredox/nickel dual catalysis is described. This transformation transpires with high linear and E-selectivity, avoiding the requirement of harsh conditions (e.g., strong base, elevated temperature). Additionally, using aryl sulfinate salts as radical precursors, allyl sulfones can also be obtained. Kinetic isotope effect experiments implicated oxidative addition of the nickel catalyst to the allylic electrophile as the turnover-limiting step, supporting previous computational studies.

Conjugated Microporous Polymer as Heterogeneous Ligand for Highly Selective Oxidative Heck Reaction

A series of pyridine-type ligands containing C C bonds were designed and synthesized for selective oxidative Heck reaction. These ligands were utilized as functional units and integrated into the skeleton of conjugated microporous polymers. 6,6′-diiodo-2,2′-bipyridine and 1,3,5-triethynylbenzene were polycondensed via Sonogashira cross-coupling strategy to afford CMP-1 material. The resultant CMP-1 was used as a heterogeneous catalytic ligand for the PdII-catalyzed oxidative Heck reaction with high linear selectivity. The linear selectivity of CMP-1 is about 30 times higher than that of bipyridine-based monomer ligand. This work opens a new front of using CMP as an intriguing platform for developing highly efficient catalysts in controlling the regioselectivity in organic reactions.