55933-91-0Relevant articles and documents
Resourceful treatment method of picloram solid residues
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Paragraph 0054-0058, (2020/11/23)
The invention relates to a picloram solid residue resourceful treatment method which comprises the following steps: a) carrying out decarboxylation reaction on picloram solid residues, performing filtering, taking filtrate, and separating out solid; b) sequentially carrying out diazotization and chlorination reaction on the solid obtained in the step a), separating out the solid, performing filtering, taking a filter cake, and performing separating to obtain 2, 3, 4, 5-tetrachloropyridine; c) subjecting the 2, 3, 4, 5-tetrachloropyridine obtained in the step b) to a dechlorination reaction soas to obtain 2, 3, 5-trichloropyridine and/or 2, 5-dichloropyridine. According to the resourceful treatment method provided by the invention, the picloram solid residues can be converted into 2, 3, 5-trichloropyridine products with good market demand prospects and relatively high economic values, and further efficient utilization of the picloram solid residues is realized.
An improved large scale synthesis of 2-amino-4-chloropyridine and its use for the convenient preparation of various polychlorinated 2-aminopyridines
Gudmundsson, Kristjan S.,Hinkley, Jack M.,Brieger, Michael S.,Drach, John C.,Townsend, Leroy B.
, p. 861 - 870 (2007/10/03)
An efficient large scale synthesis of 2-amino-4-chloropyridine (3) has been achieved through a modification of existing literature procedures. Compound 3 was used to prepare the previously unreported 2-amino-4,5-dichloropyridine (4). The known 2-amino-3,4-dichloropyridine (5) and 2-amino-3,4,5-trichloropyridine (6) were pepared from 3 by new routes and in higher yields than previously reported.