5597-69-3

Basic information

• Product Name: Bicyclo[2.2.1]hepta-2,5-diene-7-carboxylic acid, methyl ester (9CI)
• Synonyms: Bicyclo[2.2.1]hepta-2,5-diene-7-carboxylic acid, methyl ester (9CI)
• CAS NO: 5597-69-3
• Molecular Formula: C₉H₁₀O₂
• Molecular Weight: 150.1745
• Product Categories: CARBOXYLICESTER
• Mol File: 5597-69-3.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Bicyclo[2.2.1]hepta-2,5-diene-7-carboxylic acid, methyl ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]hepta-2,5-diene-7-carboxylic acid, methyl ester (9CI)(5597-69-3)
• EPA Substance Registry System: Bicyclo[2.2.1]hepta-2,5-diene-7-carboxylic acid, methyl ester (9CI)(5597-69-3)

Safety Data

• Hazardous Substances Data: 5597-69-3(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 5597-66-0 bicyclo<2.2.1>hepta-2,5-diene-7-carboxylic acid 
• 1609-39-8 7-chlorobicyclo<2.2.1>hepta-2,5-diene 

Downstream Products

• 82478-53-3 C₁₆H₁₈N₂O₂S 
• 345649-51-6 C₁₇H₁₇⁽²⁾HN₂O₄S 

Relevant articles and documents

7-LITHIO-NORBORNADIENE

A synthesis of the title compound is described as well as its reactions with some electrophiles.

Gas Chromatographic Determination of the Absolute Configuration of Secondary Alcohols and Ketones Having 7-Carboxybicycloheptane Skeleton

Stereoisomers of 7-carboxy- and/or 7-methoxycarbonylbicycloheptan-2-ol, heptan-2-one, hept-5-en-2-ol, and hept-5-en-2-one were prepared as the racemic and enantiomerically pure forms.Gas chromatographic enantiomer separation of these compounds was investigated for their diastereomeric derivatives prepared with eight chiral reagents.Among them, (R)-(-)-1-(1-naphthyl)ethyl isocyanate and (R)-(+)-α-methylbenzylamine were the most effective reagents for the hydroxy esters and keto acids, respectively, from the point of complete resolution of the enantiomers on OV-1 capillary columns.The peak components were assigned including the absolute configuration.