56003-60-2Relevant articles and documents
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Desobry,V.,Margaretha,P.
, p. 2161 - 2163 (1975)
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Micellar-system-mediated direct fluorination of ketones in water
Stavber, Gaj,Zupan, Marko,Stavber, Stojan
scheme or table, p. 589 - 594 (2009/07/09)
A micellar system was developed and applied for direct regioselective fluorination of a variety of cyclic and acyclic ketones to α-fluoroketones in water as reaction medium with Selectfluor F-TEDA-BF4 as fluorinating reagent. The inexpensive ionic amphiphile sodium dodecyl sulfate (SDS) was found to be an excellent promoter for fluorofunctionalization of hydrophobic ketones without prior activation or use of acid catalysts. Georg Thieme Verlag Stuttgart.
Direct α-fluorination of ketones using N-F reagents
Stavber, Stojan,Jereb, Marjan,Zupan, Marko
, p. 2609 - 2615 (2007/10/03)
The use of 1-fluoro-4-hydroxy-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Accufluor NFTh) as a fluorine atom transfer reagent and methanol as solvent enabled direct regiospecific fluorofunctionalization of the α-carbonyl position in ketones w