56030-48-9

Basic information

• Product Name: 1,3-Propanediol, 2-methylene-1-phenyl-
• CAS NO: 56030-48-9
• Molecular Formula: C10H12O2
• Molecular Weight: 164.204
• Mol File: 56030-48-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,3-Propanediol, 2-methylene-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Propanediol, 2-methylene-1-phenyl-(56030-48-9)
• EPA Substance Registry System: 1,3-Propanediol, 2-methylene-1-phenyl-(56030-48-9)

Safety Data

• Hazardous Substances Data: 56030-48-9(Hazardous Substances Data)

Upstream product

• 164853-29-6 (±)-methyl 2-{[(tert-butyldimethylsilyl)oxy](phenyl)methyl}prop-2-enoate 
• 100-52-7 benzaldehyde 
• 18020-59-2 methyl 3-hydroxy-2-methylidene-3-phenylpropionate 
• 868659-35-2 (+/-)-2-[(tert-butyldimethylsilyloxy)(phenyl)methyl]-2-prop-2-en-1-ol 
• 84201-43-4 2-iodoprop-2-en-1-ol 
• 598-19-6 2-bromoallyl alcohol 

Downstream Products

• 1058138-92-3 1-(4-methoxyphenyl)-4-methylene-2-styrylpyrrolidine 
• 1058138-76-3 2-methylene-1-phenylpropane-1,3-bisbenzyl ether 

Relevant articles and documents

Convenient synthesis of pyrrolidines by amphiphilic allylation of imines with 2-methylenepropane-1,3-diols

(Chemical Equation Presented). A straightforward route: The combination of a palladium catalyst and triethylborane promotes the amphiphilic (nucleophilic-electrophilic) allylation of aldimines, prepared in situ from a wide variety of aromatic and aliphatic aldehydes and amines, with commercially available 2-methylenepropane-1,3-diols to provide pyrrolidines (see scheme).

An improved procedure for the preparation of the O,2-dianion of allyl alcohol

An improved procedure for the preparation of the O,2-dianion of allyl alcohol is described. The use of the magnesium alkoxide of 2-bromopropen-1- ol instead of the known lithium salt, suppresses dehydrohalogenation upon treatment with tert-butyl lithium a