5615-90-7

Basic information

• Product Name: NSC210729
• Synonyms: NSC210729;3-METHYL-PYRROLIDINE-2,5-DIONE;2-Methylsuccinimide;3-Methyl-2,5-pyrrolidinedione
• CAS NO: 5615-90-7
• Molecular Formula: C₅H₇NO₂
• Molecular Weight: 113.1146
• Mol File: 5615-90-7.mol
• Article Data: 1

Chemical Properties

• Melting Point: 65-66 °C
• Boiling Point: 267.7°Cat760mmHg
• Flash Point: 140.5°C
• Appearance: /
• Density: 1.157g/cm³
• Vapor Pressure: 1.06E-08mmHg at 25°C
• Refractive Index: 1.616
• Storage Temp.: 2-8°C
• PKA: 9.66±0.50(Predicted)
• CAS DataBase Reference: NSC210729(CAS DataBase Reference)
• NIST Chemistry Reference: NSC210729(5615-90-7)
• EPA Substance Registry System: NSC210729(5615-90-7)

Safety Data

• Hazardous Substances Data: 5615-90-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H20N2O3/c1-2-5-11-12(18-19)10-13(14-6-3-8-20-14)17-16(11)15-7-4-9-21-15/h3-4,6-9,11,13,16-17,19H,2,5,10H2,1H3/b18-12-

Upstream product

• 67-56-1 methanol 
• 201230-82-2 carbon monoxide 
• 79-39-0 Methacrylamide 

Downstream Products

• 137271-80-8 [(S)-2-Methyl-1-((3R,4S)-4-methyl-2,5-dioxo-pyrrolidine-3-carbonyl)-propyl]-carbamic acid benzyl ester 
• 137331-58-9 [(S)-2-Methyl-1-((3S,4R)-4-methyl-2,5-dioxo-pyrrolidine-3-carbonyl)-propyl]-carbamic acid benzyl ester 
• 54281-57-1 3-benzoyl-4-methyl-pyrrolidine-2,5-dione 
• 128561-73-9 1-(2-(benzyloxymethyl)-3-butenyl)-3-methyl-2,5-pyrrolidinedione 
• 33425-47-7 3,4-dimethylpyrrolidine-2,5-dione 
• 128866-07-9 (+/-)-(E)-3-(4-Hydroxyphenyl)-N-[4-(3-methyl-2,5-dioxo-1-pyrrolidinyl)butyl]-2-propenamide 
• 150254-86-7 (+/-)-(E)-3-(4-Methoxyphenyl)-N-<4-(3-methyl-2,5-dioxo-1-pyrrolidinyl)butyl>-2-propenamide 
• 128562-16-3 1-(2-(benzyloxymethyl)-3-butenyl)-5-ethoxy-4-methyl-2-pyrrolidinone 
• 128562-13-0 1-(2-(benzyloxymethyl)-3-butenyl)-5-ethoxy-3-methyl-2-pyrrolidinone 
• 128562-03-8 rel-(6S,7R,8aR)-6-(benzoyloxymethyl)-7-(3,5-dinitrobenzoyloxy)hexahydro-1-methyl-3(2H)-indolizinone 
• 124817-99-8 (3S,4R)-andrimid 
• 270075-30-4 methyl 3-((methoxycarbonyl)amino)-2-methylpropanoate 
• 116173-78-5 methyl 3-((methoxycarbonyl)amino)-3-methylpropanoate 

Relevant articles and documents

Carbonylation (hydroformylation and hydrocarbalkoxylation) and enantioselective carbonylation of some methacrylic acid derivatives

The hydroformylation of methyl methacrylate (1) or t-butyl methacrylate (2) takes place with fair to good chemoselectivity, the regioselectivity depending on the catalyst precursor used.By contrast, methacrylonitrile (3), methacrylamide (4), and N-benzyl-methacrylamide (5) undergo hydroformylation followed by subsequent reactions.The formyl product formed is reduced to the corresponding 2-cyano-2-methylpropan-1-ol in the case of 3, and undergoes cyclization to 2-methyl-2,3-dehydrobutyrolactames for 4 and 5.Under conditions of hydrocarbalkoxylation in the presence of palladium catalysts, 4 gives 3-methylsuccinimide.In the enantioselective reactions, extents of asymmetric induction of about 20-50percent have been obtained.