56185-11-6

Basic information

• Product Name: Phosphoramidochloridic acid, dimethyl-, phenyl ester
• CAS NO: 56185-11-6
• Molecular Formula: C8H11ClNO2P
• Molecular Weight: 219.608
• Mol File: 56185-11-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phosphoramidochloridic acid, dimethyl-, phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphoramidochloridic acid, dimethyl-, phenyl ester(56185-11-6)
• EPA Substance Registry System: Phosphoramidochloridic acid, dimethyl-, phenyl ester(56185-11-6)

Safety Data

• Hazardous Substances Data: 56185-11-6(Hazardous Substances Data)

Upstream product

• 108-95-2 phenol 
• 677-43-0 N,N-dimethylphosphoroamidic dichloride 
• 680-31-9 N,N,N,N,N,N-hexamethylphosphoric triamide 
• 139-02-6 sodium phenoxide 

Downstream Products

• 1644559-09-0 C₁₃H₁₆N₂O₂P⁽¹⁺⁾*Cl^(1-) 
• 1644559-12-5 C₁₅H₁₈N₂O₃P⁽¹⁺⁾*Cl^(1-) 
• 1644559-11-4 C₁₅H₁₈N₂O₃P⁽¹⁺⁾*Cl^(1-) 
• 1644559-10-3 C₁₉H₂₀N₂O₂P⁽¹⁺⁾*Cl^(1-) 

Relevant articles and documents

Kinetics and mechanism of the anilinolysis of aryl N,N-dimethyl phosphoroamidochloridates in acetonitrile

The nucleophilic substitution reactions of Y-aryl N,N-dimethyl phosphoroamidochloridates with substituted anilines and deuterated anilines are kinetically investigated in acetonitrile at 65.0 °C. A stepwise mechanism with a rate-limiting leaving group departure from the intermediate is proposed based on the positive pXY value. The deuterium kinetic isotope effects involving deuterated anilines show secondary inverse with all the nucleophiles, rationalized by a dominant backside nucleophilic attack.