56185-14-9

Basic information

• Product Name: n-propyl 4-dimethylaminobenzoate
• Synonyms: n-propyl 4-dimethylaminobenzoate
• CAS NO: 56185-14-9
• Molecular Weight: 207.272
• Mol File: 56185-14-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: n-propyl 4-dimethylaminobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: n-propyl 4-dimethylaminobenzoate(56185-14-9)
• EPA Substance Registry System: n-propyl 4-dimethylaminobenzoate(56185-14-9)

Safety Data

• Hazardous Substances Data: 56185-14-9(Hazardous Substances Data)

Upstream product

• 71-23-8 propan-1-ol 
• 619-84-1 p-N,N-dimethylaminobenzoic acid 
• 680-31-9 N,N,N,N,N,N-hexamethylphosphoric triamide 
• 94-13-3 nipasol 
• 100-10-7 4-dimethylamino-benzaldehyde 

Relevant articles and documents

Addition reactions and redox esterifications of carbonyl compounds by N-heterocyclic carbenes of indazole

Thermal decarboxylation converts 1,2-dimethylindazolium-3-carboxylate into indazol-3-ylidene, which reacts in situ with ketones to form stable 1:1 adducts. When the reaction is conducted with aromatic aldehydes in alcohols, redox esterifications to benzoates are observed. Model reactions such as redox esterifications of aromatic aldehydes with sodium alcoholates in the presence of 1,2-dimethylindazolium salt and oxidations of sodium benzylates by 1,2-dimethylindazolium salt to aldehydes lend support to a Cannizzaro-type mechanism of this reaction.