5619-82-9Relevant articles and documents
Reductive alkylation of active methylene compounds with carbonyl derivatives, calcium hydride and a heterogeneous catalyst
Guyon, Carole,Duclos, Marie-Christine,Sutter, Marc,Métay, Estelle,Lemaire, Marc
, p. 7067 - 7075 (2015/06/25)
A one-pot two-step reaction (Knoevenagel condensation - reduction of the double bond) has been developed using calcium hydride as a reductant in the presence of a supported noble metal catalyst. The reaction between carbonyl compounds and active methylene
Clay-mediated Synthesis of gem-Bis(alkoxycarbonyl) Alkenes under Microwave Irradiation
Ayoubi, Sahar Abdallah-El,Texier-Boullet, Francoise
, p. 208 - 209 (2007/10/03)
Diethyl and dimethyl malonate react selectively with aldehydes to afford alkenes within a few minutes, by adsorption on acidic clay (Montmorillonite K10) in a solvent-free reaction under microwave irradiation in a domestic oven.