56221-90-0

Basic information

• Product Name: (3E)-tetradec-3-en-1-yl acetate
• Synonyms: (3E)-3-Tetradecenyl acetate; (3E)-Tetradec-3-en-1-yl acetate; 3-tetradecen-1-ol, acetate, (3E)-; E-3-Tetradecen-1-ol acetate
• CAS NO: 56221-90-0
• Molecular Formula: C₁₆H₃₀O₂
• Molecular Weight: 254.4082
• Mol File: 56221-90-0.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 326.4°C at 760 mmHg
• Flash Point: 93.9°C
• Density: 0.878g/cm³
• Vapor Pressure: 0.000216mmHg at 25°C
• Refractive Index: 1.45
• CAS DataBase Reference: (3E)-tetradec-3-en-1-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (3E)-tetradec-3-en-1-yl acetate(56221-90-0)
• EPA Substance Registry System: (3E)-tetradec-3-en-1-yl acetate(56221-90-0)

Safety Data

• Hazardous Substances Data: 56221-90-0(Hazardous Substances Data)

Upstream product

• 127-08-2 potassium acetate 
• 139489-34-2 1-bromo-tetradec-(3E)-en 
• 54897-65-3 (Z)-3-Tetradecen-1-ol acetate 
• 108-24-7 acetic anhydride 
• 68900-86-7 trans-3-tetradecen-1-ol 
• 112-54-9 Dodecanal 
• 75730-21-1 trans-3-tetradecenoic acid 
• 139489-32-0 1-cyclopropyl-undecan-1-ol 
• 75-36-5 acetyl chloride 
• 112-29-8 1-bromo dodecane 

Downstream Products

• 68900-86-7 trans-3-tetradecen-1-ol 

Relevant articles and documents

Method for synthesizing cis-3-tetradecanoacetate and trans-3-tetradecanoacetate

The invention discloses a method for synthesizing cis-3-tetradecanoacetate and trans-3-tetradecanoacetate. The method comprises the following steps: (1) preparing 3-tetradecyne alcohol-1; (2) preparing cis-3-tetradecenol-1; (3) preparing trans-3-tetradecenol-1; and (4) preparing the cis-3-tetradecanoacetate and trans-3-tetradecanoacetate. The method is used for synthesizing cis-3-tetradecanoacetate and trans-3-tetradecanoacetate which are main components of gyplure of holcocerus insularis Staudinger; the raw materials for reaction are easily obtained; the cost is low; technical processes are short; reaction conditions are mild; the operation is simple, convenient and free from risk; the product is easily separated; the yield is high; and massive production can be carried out.

SYNTHESIS OF 3E-TETRADECENOL, 3E,9E-TETRADECADIENOL, AND THEIR ACETATES STARTING FROM ACETYLCYCLOPROPANE

Stereospecific synthesis of the linear E-olefins mentioned in the title was realized by a general scheme that was worked out earlier by the authors and which includes as key step homologization of the corresponding aliphatic pentakisnoraldehydes by means of trimethylsilyloxyvinylcyclopropane and ZnBr2-initiated rearrangement of the intermediate cyclopropylcarbinols under the influence of Me3SiBr.