56240-58-5Relevant articles and documents
Coordinatively unsaturated Ru(II) species Ru(xantsil)(CO): A new active catalyst for oligomerization/deoligomerization of HSiMe2SiMe3 [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]. Isolation of a stabilized form of the silyl(silylene) intermediates
Minglana, Jim Josephus G.,Okazaki, Masaaki,Tobita, Hiromi,Ogino, Hiroshi
, p. 406 - 407 (2002)
Ru(xantsil)(CO)(η6-C6H5CH3) (1) was found to be a catalyst for the oligomerization/deoligomerization of HSiMe2SiMe3 to give H(SiMe2)nMe (n = 1-8). A possible mechanism involving a silyl(silylene) intermediate was strongly supported by the isolation of its stabilized form, i.e., alkoxy-bridged bis(silylene) complex which was characterized by X-ray crystal structure analysis.
FORMATION AND REACTIONS OF DIMETHYLSILYLENE AND DIMETHYLGERMYLENE
Nefedov, O. M.,Skell, Philip S.
, p. 320 - 322 (2007/10/02)
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