56318-28-6

Basic information

• Product Name: (bis(allyloxy)methyl)benzene
• Synonyms: (bis(allyloxy)methyl)benzene
• CAS NO: 56318-28-6
• Molecular Weight: 204.269
• Mol File: 56318-28-6.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: (bis(allyloxy)methyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (bis(allyloxy)methyl)benzene(56318-28-6)
• EPA Substance Registry System: (bis(allyloxy)methyl)benzene(56318-28-6)

Safety Data

• Hazardous Substances Data: 56318-28-6(Hazardous Substances Data)

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 107-18-6 allyl alcohol 
• 16754-50-0 triallyl orthoformate 
• 100-52-7 benzaldehyde 
• 5153-67-3 nitrostyrene 
• 18146-00-4 allyloxytrimethylsilane 
• 4460-46-2 3-chloro-3-phenyl-3H-diazirine 
• 774-48-1 (diethoxymethyl)benzene 
• 431-47-0 trifluoroacetic acid-methyl ester 
• 20907-32-8 sodium allyloxide 

Downstream Products

• 1309647-50-4 C₁₅H₁₈O₄ 
• 14593-43-2 benzyl allyl ether 
• 1434139-83-9 (E)-ethyl 3,5-bis(allyloxy)-5-phenylpent-2-enoate 
• 1334180-50-5 (4S)-N-[(3S)-3-allyloxy-3-phenylpropanoyl]-4-tert-butyl-1,3-thiazolidine-2-thione 
• 1334180-51-6 (4S)-N-[(3R)-3-allyloxy-3-phenylpropanoyl]-4-tert-butyl-1,3-thiazolidine-2-thione 
• 165170-94-5 (5S,9S)-9-methyl-2-phenyl-9-vinyl-1,7-dioxaspiro[4.4]non-2-ene-4,6-dione 
• 1334180-38-9 ethyl (R)-2-diazo-5-[(2E)-3-methyl-4-(trimethylsilyloxy)but-2-enyloxy]-3-oxo-5-phenylpentanoate 
• 1334180-37-8 ethyl (R)-2-diazo-5-[(2E)-3-methyl-4-hydroxybut-2-enyloxy]-3-oxo-5-phenylpentanoate 
• 1334180-24-3 ethyl (R)-2-diazo-5-[(2E)-3-methyl-4-oxobut-2-enyloxy]-3-oxo-5-phenylpentanoate 
• 1334180-36-7 ethyl (R)-2-diazo-3-oxo-5-(2-oxoethoxy)-5-phenylpentanoate 
• 1334180-23-2 ethyl (R)-5-(allyloxy)-2-diazo-3-oxo-5-phenylpentanoate 
• 1334180-65-2 tert-butyl 2-diazo-5-[(2E)-3-methyl-4-(trimethylsilyloxy)but-2-enyloxy]-3-oxo-5-phenylpentanoate 
• 1334180-64-1 methyl 2-diazo-5-[(2E)-3-methyl-4-(trimethylsilyloxy)but-2-enyloxy]-3-oxo-5-phenylpentanoate 
• 1334180-63-0 tert-butyl 2-diazo-5-[(2E)-3-methyl-4-hydroxybut-2-enyloxy]-3-oxo-5-phenylpentanoate 

Relevant articles and documents

Lewis Acid-Catalyzed Vinyl Acetal Rearrangement of 4,5-Dihydro-1,3-dioxepines: Stereoselective Synthesis of cis- And trans-2,3-Disubstituted Tetrahydrofurans

Lewis acid-catalyzed rearrangements of 4,5-dihydro-1,3-dioxepines have been investigated. Rearrangement of vinyl acetals under a variety of conditions resulted in cis- and trans-2,3-disubstituted tetrahydrofuran derivatives in a highly stereoselective man

Preparation of acetals from aldehydes and alcohols under basic conditions

A new, simple protocol for the synthesis of acetals under basic conditions from non-enolizable aldehydes and alcohols has been reported. Such reactivity is facilitated by a sodium alkoxide along with a corresponding trifluoroacetate ester, utilizing formation of sodium trifluoroacetate as a driving force for acetal formation. The usefulness of this protocol is demonstrated by its orthogonality with various acid-sensitive protecting groups and by good compatibility with functional groups, delivering synthetically useful acetals complementarily to the synthesis under acidic conditions from aldehydes and alcohols.

Lewis acid-promoted intermolecular acetal-initiated cationic polyene cyclizations

This paper describes a highly efficient intermolecular biomimetic polyene cyclization method using acetal as initiators. Both good yield and asymmetric induction were obtained. Copyright