5636-54-4

Basic information

• Product Name: N-{2-[(2E)-2-{[3-bromo-4-(dimethylamino)phenyl]methylidene}hydrazino]-1-methyl-2-oxoethyl}-N-(4-methoxyphenyl)methanesulfonamide (non-preferred name)
• CAS NO: 5636-54-4
• Molecular Formula: C₂₂H₂₃N
• Molecular Weight: 497.4059
• Mol File: 5636-54-4.mol
• Article Data: 15

Chemical Properties

• Density: 1.37g/cm³
• Refractive Index: 1.593
• CAS DataBase Reference: N-{2-[(2E)-2-{[3-bromo-4-(dimethylamino)phenyl]methylidene}hydrazino]-1-methyl-2-oxoethyl}-N-(4-methoxyphenyl)methanesulfonamide (non-preferred name)(CAS DataBase Reference)
• NIST Chemistry Reference: N-{2-[(2E)-2-{[3-bromo-4-(dimethylamino)phenyl]methylidene}hydrazino]-1-methyl-2-oxoethyl}-N-(4-methoxyphenyl)methanesulfonamide (non-preferred name)(5636-54-4)
• EPA Substance Registry System: N-{2-[(2E)-2-{[3-bromo-4-(dimethylamino)phenyl]methylidene}hydrazino]-1-methyl-2-oxoethyl}-N-(4-methoxyphenyl)methanesulfonamide (non-preferred name)(5636-54-4)

Safety Data

• Hazardous Substances Data: 5636-54-4(Hazardous Substances Data)

Upstream product

• 5694-21-3 dibenzyl-styryl-amine 
• 100-39-0 benzyl bromide 
• 64-04-0 phenethylamine 
• 103-63-9 1-phenyl-2-bromoethane 
• 103-49-1 dibenzylamine 
• 57684-32-9 N-((1 H-benzo[d][1,2,3]triazol-1-yl)methyl)-N-benzyl-1-phenylmethanamine 
• 6921-34-2 benzylmagnesium chloride 
• 3459-92-5 DBC 
• 100-42-5 styrene 
• 591-50-4 iodobenzene 
• 591-51-5 phenyllithium 
• 122-78-1 phenylacetaldehyde 
• 100-51-6 benzyl alcohol 
• 52742-32-2 N,N-dibenzyl-O-benzoylhydroxylamine 

Downstream Products

• 156-28-5 2-phenylethylamine hydrochloride 

Relevant articles and documents

Reversal of polarity by catalytic SET oxidation: Synthesis of azabicyclo[: M. n.0]alkanes via chemoselective reduction of amidines

A one-pot catalytic method has been developed for the stereoselective synthesis of cyclopropane-fused cyclic amidines using CuBr2/K2S2O8 as an efficient single electron transfer (SET) oxidative system. The generality of this mild method is demonstrated with a wide variety of substrates to furnish pharmaceutically important amidines containing aza-bicyclic and novel aza-tricyclic frameworks in very good yields. A chemoselective reduction of cyclic amidines to 2-/3-azabicyclo[m.n.0]alkanes and octahydroindoles has been developed using a NaBH4/I2 reagent system. The synthetic scope of the chemoselective reduction of the amidine functionality has been exemplified in the stereoselective synthesis of an iminosugar based (±)-epiquinamide analogue. This journal is

B(C6F5)3-catalyzed tandem protonation/deuteration and reduction of: In situ -formed enamines

A highly efficient B(C6F5)3-catalyzed tandem protonation/deuteration and reduction of in situ-formed enamines in the presence of water and pinacolborane was developed. Regioselective β-deuteration of tertiary amines was achieved with high chemo- and regioselectivity. D2O was used as a readily available and cheap source of deuterium. Mechanistic studies indicated that B(C6F5)3 could activate water to promote the protonation and reduction of enamines. This journal is

Method of producing higher amine (by machine translation)

PROBLEM TO BE SOLVED: To provide a method of producing a secondary or tertiary higher amine. SOLUTION: The method of producing a higher amine comprises allowing a primary or secondary amine to react with an alcohol in the presence of at least one species of hydrogen halide selected from hydrogen chloride, hydrogen bromide and hydrogen iodide, or in the presence of a compound capable of producing a hydrogen halide (such as 1,3,5-triazo-2,4,6-triphosphorine-2,2,4,4,6,6-chloride). If the raw material amine is a primary amine, a secondary higher amine and a tertiary higher amine can be produced. If the raw material amine is a secondary amine, a tertiary higher amine can be produced. COPYRIGHT: (C)2012,JPO&INPIT