566198-50-3

Basic information

• Product Name: 1,2-Hydrazinedicarboxylic acid, 1-[(1S,2R)-2-hydroxy-3,3-dimethoxy-1-(methoxycarbonyl)propyl]-, bis(phenylmethyl) ester
• CAS NO: 566198-50-3
• Molecular Formula: C23H28N2O9
• Molecular Weight: 476.483
• Mol File: 566198-50-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2-Hydrazinedicarboxylic acid, 1-[(1S,2R)-2-hydroxy-3,3-dimethoxy-1-(methoxycarbonyl)propyl]-, bis(phenylmethyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Hydrazinedicarboxylic acid, 1-[(1S,2R)-2-hydroxy-3,3-dimethoxy-1-(methoxycarbonyl)propyl]-, bis(phenylmethyl) ester(566198-50-3)
• EPA Substance Registry System: 1,2-Hydrazinedicarboxylic acid, 1-[(1S,2R)-2-hydroxy-3,3-dimethoxy-1-(methoxycarbonyl)propyl]-, bis(phenylmethyl) ester(566198-50-3)

Safety Data

• Hazardous Substances Data: 566198-50-3(Hazardous Substances Data)

Upstream product

• 60705-25-1 4,4-dimethoxy-3-oxo-butyric acid methyl ester 
• 2449-05-0 dibenzyl azodicarboxylate 
• 569308-28-7 (R)-3-Hydroxy-4,4-dimethoxy-butyric acid methyl ester 

Downstream Products

• 566198-51-4 C₂₉H₄₂N₂O₉Si 

Relevant articles and documents

Diastereoselective syntheses of α-amino-β-hydroxyesters precursors of the ribosyl-diazepanone core of the liposidomycins

The diastereoselective syntheses of the O-protected ribosyl-β-hydroxy-α-amino esters 3 and 4, precursors of α-ribosyl-diazepanone core analogues of the liposidomycins, respectively, from the β-ketoesters 5 and 6 are described. The anti relationship between the two adjacent aminated and hydroxylated carbons was controlled by sequential hydrogenation of the β-ketoesters in the presence of chiral ruthenium catalysts and electrophilic amination of the resulting β-hydroxyesters.