56685-62-2Relevant articles and documents
Nucleophilic α-addition to β-nitroacrylates: application to the synthesis of α-thioacrylates
Lewandowska, Elzbieta
, p. 4879 - 4883 (2007/10/03)
The α-addition of alkyl or aryl thionucleophiles to β-nitro-α,β-unsaturated alkenoates in THF in the presence of TEA or DBU gave access to the α-thio-α,β-unsaturated alkenoates. The reaction occurred via formation of β-nitro-α-thioalkanoates and concomitant elimination of nitrous acid from the α-adducts.
ELIMINATIVE DEOXYGENATION: A FACILE SYNTHESIS OF α-CYANO AND α-CARBOALKOXY SUBSTITUTED VINYL SULFIDES
Miller, R. D.,Haessig, R.
, p. 2395 - 2398 (2007/10/02)
The facile eliminative deoxygenation of α-cyano and carboalkoxy sulfoxides by trimethylsilyl triflate under mildly basic conditions results in the formation of α-thiophenyl substituted α,β-unsaturated nitriles and esters in high yields.
NEW ACETYLENIC MICHAEL RECEPTOR EQUIVALENTS. PART I : SYNTHESIS OF α-SULFENYL - AND α-SULFINYL ACRYLIC DERIVATIVES.
Leyendecker, Francois,Comte, Marie-Therese
, p. 5031 - 5034 (2007/10/02)
The synthesis of α-thioarylated β-unsubstituted acrilic derivatives is reported.