56734-76-0Relevant articles and documents
A novel synthesis of α-(perfluoroalkyl) ketones
Hu, Chang-Ming,Tang, Xiao-Qing,Qing, Feng-Ling
, p. 405 - 407 (2007/10/02)
Reaction of sodium perhalofluoroalkyl sulfinates with alkenes under UV irradiation and oxygen atmosphere provides α-perhalofluoroalkyl ketones in good yields.
TRIETHYLBORANE INDUCED PERFLUOROALKYLATION OF SILYL ENOL ETHERS OR GERMYL ENOL ETHERS WITH PERFLUOROALKYL IODIDES
Miura, Katsukiyo,Taniguchi, Masahiko,Nozaki, Kyoko,Oshima, Koichiro,Utimoto, Kiitiro
, p. 6391 - 6394 (2007/10/02)
Reaction of perfluoralkyl iodides with silyl enol ethers mediated by Et3B in the presence of a base provides perfluoroalkylated silyl enol ethers.Meanwhile, treatment of germyl enol ethers with perfluoroalkyl iodides affords α-perfluoroalkyl ketones in good yields.