569-15-3

Basic information

• Product Name: PHENANTHRENE-1,4-DIONE
• Synonyms: PHENANTHRENE-1,4-DIONE;1,4-phenanthraquinone;1,4-phenanthrenedione;1,4-phenanthrenequinone;1,4-phenanthroquinone;phenanthrene-1,4-quinone
• CAS NO: 569-15-3
• Molecular Formula: C₁₄H₈O₂
• Molecular Weight: 208.21
• Mol File: 569-15-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 406°Cat760mmHg
• Flash Point: 152°C
• Appearance: /
• Density: 1.328g/cm³
• Vapor Pressure: 8.39E-07mmHg at 25°C
• Refractive Index: 1.702
• CAS DataBase Reference: PHENANTHRENE-1,4-DIONE(CAS DataBase Reference)
• NIST Chemistry Reference: PHENANTHRENE-1,4-DIONE(569-15-3)
• EPA Substance Registry System: PHENANTHRENE-1,4-DIONE(569-15-3)

Safety Data

• Hazardous Substances Data: 569-15-3(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of Heterocyclic Chemistry, 28, p. 29, 1991 DOI: 10.1002/jhet.5570280105The Journal of Organic Chemistry, 42, p. 3463, 1977 DOI: 10.1021/jo00442a001

InChI:InChI=1/C14H8O2/c15-12-7-8-13(16)14-10-4-2-1-3-9(10)5-6-11(12)14/h1-8H

Upstream product

• 85-01-8 phenanthrene 
• 82650-72-4 1-bromo-4-benzoyloxyimino-1,2,3,4-tetrahydrophenanthrene 

Downstream Products

• 33929-61-2 1,4-diacetoxy-phenanthrene 
• 24903-46-6 Phenanthro<2,3-h>isoquinoline 
• 24903-48-8 phenanthro<3.2-h>isoquinoline 
• 133620-01-6 N-benzoyl-1,2,3,4,7,14-hexahydrophenanthro<3.2-h>isoquinoline 
• 133620-02-7 N-benzoyl-1,2,3,4,7,14-hexahydrophenanthroy<2.3-h>isoquinoline 
• 133619-99-5 N-Benzoyl-1,2,3,4-tetrahydrophenanthro<3.2-h>isoquinoline-7,14-dione 
• 133620-00-5 N-Benzoyl-1,2,3,4-tetrahydrophenanthro<2.3-h>isoquinoline-7,14-dione 

Relevant articles and documents

Photocatalytic degradation of polycyclic aromatic hydrocarbons in GaN:ZnO solid solution-assisted process: Direct hole oxidation mechanism

GaN:ZnO exhibits excellent activity for the photodegradation of PAHs, and the activity can be obviously improved by loading Pt. The degradation of PAHs in the system of GaN:ZnO is induced by the formation of holes. The holes generated then interact with PAHs to produce PAHs+, which is active enough to react with O2.

OXYGENATION OF AROMATIC AND ALIPHATIC HYDROCARBONS BY A NEW REAGENT SYSTEM, Fe(CH3CN)6(2+)-H2O2-Ac2O: AN EFFECTIVE MODEL REAGENT FOR MONO-OXYGENASE

Reactions of aromatic and aliphatic hydrocarbons with a new system, Fe(CH3CN)6(2+) - H2O2 - Ac2O in CH3CN, gave oxygenation products with fairly high reaction efficiency ( Tables I and II )compared to known to reagent systems used as enzyme models for mono-oxygenases.Investigations of the mechanism of these reactions indicated the involvement of either complex C.FeIV(OH)(OAc)(2+), or complex D, FeIV(OAc)(2+), dependig on the organic substrate.Keywords-oxygenation; aromatic hydrocarbon; aliphatic hydrocarbon; hexakisacetonitrile iron(II) perchlorate; hydrogen peroxide; enzyme model; mono-oxygenase