56955-34-1

Basic information

• Product Name: Cyclopropanol, 2-(4-chlorophenyl)-1-methoxy-
• CAS NO: 56955-34-1
• Molecular Formula: C10H11ClO2
• Molecular Weight: 198.649
• Mol File: 56955-34-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclopropanol, 2-(4-chlorophenyl)-1-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropanol, 2-(4-chlorophenyl)-1-methoxy-(56955-34-1)
• EPA Substance Registry System: Cyclopropanol, 2-(4-chlorophenyl)-1-methoxy-(56955-34-1)

Safety Data

• Hazardous Substances Data: 56955-34-1(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 463-51-4 Ketene 
• 19277-54-4 p-chlorophenyldiazomethane 

Downstream Products

• 56955-41-0 1-Methoxy-3-(p-chlorophenyl)-2-propanon 
• 90919-31-6 1-methoxy-1-(4-chlorophenyl)-2-propanone 
• 56955-46-5 1-n-Propoxy-3-(p-chlorophenyl)-2-propanon 
• 56955-45-4 1-n-Propoxy-1-(p-chlorophenyl)-2-propanon 
• 56955-44-3 n-Propyl-3-(p-chlorophenyl)-propionat 
• 56955-39-6 1-(4-chlorophenyl)-2-oxopropyl acetate 
• 56955-38-5 3-(4-chlorophenyl)-2-oxopropyl acetate 
• 50561-69-8 methyl 3-(4-chlorophenyl)propanoate 
• 54836-54-3 2-(4-chlorophenyl)cyclopropanone dimethyl acetal 

Relevant articles and documents

Electron Transfer Profile of Cyclopropanone Acetals in the Nonirradiated Reaction with Tetracyanoethylene, Chloranil, and Dicyanodichlorobenzoquinone

The donor profiles of cyclopropanone acetals 1 and 2 were examined in the reactions with electron acceptors (TCNE, DDQ, chloranil, and 1-cyanonaphthalene).With TCNE under nonirradiating conditions, an exclusive 2 + 2 cycloaddition took place stereospecifically with monosubstituted acetals 1a-c but nonstereospecifically with disubstituted acetals 1d,e.With quinones, a ring-opening of the cyclopropane and its coupling with the quinone took place to give the C (cyclopropane)-O (quinone) adduct 9 (with chloranil) or 10 (with DDQ), the latter of which underwent the elimination of a phenol to produce unsaturated esters 5 and 6.In addition, the intervention of the C (cyclopropane)-C (quinone) adduct 14 (with chloranil) or 15 (with DDQ), both as the precursor of 5 and 6, was also postulated.With 1-cyanonaphthalene, under photolysis, the cis/trans isomerization of 1 and 2 occured.The results provided evidences that cyclopropanone acetals, in general, are prone to function as donors.The mechanism of the reaction with quinones, in particular, was investigated in detail.