5702-29-4

Basic information

• Product Name: 2-Ethyl-1,3-dioxane
• Synonyms: 2-Ethyl-1,3-dioxane
• CAS NO: 5702-29-4
• Molecular Formula: C₆H₁₂O₂
• Molecular Weight: 0
• Mol File: 5702-29-4.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 134.8°C at 760 mmHg
• Flash Point: 35.1°C
• Appearance: /
• Density: 0.921g/cm³
• Vapor Pressure: 9.83mmHg at 25°C
• Refractive Index: 1.406
• CAS DataBase Reference: 2-Ethyl-1,3-dioxane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Ethyl-1,3-dioxane(5702-29-4)
• EPA Substance Registry System: 2-Ethyl-1,3-dioxane(5702-29-4)

Safety Data

• Hazardous Substances Data: 5702-29-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H12O2/c1-2-6-7-4-3-5-8-6/h6H,2-5H2,1H3

Upstream product

• 17230-31-8 2-methoxy-1,3-dioxane 
• 925-90-6 ethylmagnesium bromide 
• 78135-17-8 3-(1'-methoxypropoxy)-1-propanol 
• 62930-27-2 2-isopropyl-1,3,2-dioxaborinane 
• 123-38-6 propionaldehyde 
• 504-63-2 trimethyleneglycol 
• 6180-67-2 3-allyloxy-1-propanol 
• 1396797-87-7 2-(2'-fluoroethyl)-1,3-dioxane 
• 4294-57-9 para-methylphenylmagnesium bromide 

Downstream Products

• 4161-22-2 3-propoxypropanol 

Relevant articles and documents

Dinuclear iron complex-catalyzed cross-coupling of primary alkyl fluorides with aryl grignard reagents

Iron-catalyzed cross-coupling of nonactivated primary alkyl fluorides with aryl Grignard reagents has been achieved by using the low-coordinate dinuclear iron complex [(IPr2Me2)Fe(μ2-NDipp) 2Fe(IPr2Me2)] as the catalyst. This iron-catalyzed C(sp3)-F bond arylation reaction is applicable to a variety of aryl Grignard reagents and primary alkyl fluorides. The product pattern suggests the involvement of a radical-type mechanism for its C-F bond scission step.

SYNTHESIS OF CYCLIC ACETALS FROM ALDEHYDES AND DIOLS MEDIATED BY BUTYLTIN TRICHLORIDE

A facile and convenient method for the preparation of cyclic acetals from aldehydes and diols utilizing butyltin trichloride as acid catalyst and dehydrating agent is proposed.Some 2-alkyl-1,3-dioxolanes and -dioxans (alkyl = Et and i-Pr) have been prepared under mild conditions. 2-vinyl-1,3-dioxan has also been produced by transacetalization from acrolein dimethyl acetal and 1,3-propanediol.