57090-79-6Relevant articles and documents
Photolysis of 1,1,4,4-Tetraphenyl-3-buten-2-one: Ketene Formation from an Acyclic α,β-Unsaturated Ketone
Adam, Waldemar,Berkessel, Albrecht,Peters, Eva-Maria,Peters, Karl,Schnering, Hans Georg von
, p. 2811 - 2814 (2007/10/02)
1,1,4,4-Tetraphenyl-3-buten-2-one (2a) was prepared by addition of the dianion of 1,1-diphenylacetone to benzophenone.Upon direct irradiation at 300 nm, the enone 2a rearranged mainly to (1,1,2,2-tetraphenylethyl)ketene (3).Intramolecular acylation of the