5717-05-5Relevant articles and documents
PREPARATION AND ABSOLUTE CONFIGURATION AT C(22) OF 21,26,27-TRINOR-5α-CHOLESTANE-22,25-DIOL DERIVATIVES
Pouzar, Vladimir,Vasickova, Sona,Drasar, Pavel,Cerny, Ivan,Havel, Miroslav
, p. 2423 - 2436 (2007/10/02)
Reaction of 5α-pregnan-21-al (V), obtained from ester of the corresponding acid III via the alcohol IV, with lithium salt of 1-methoxymethoxy-2-propyne afforded both the isomeric 25-methoxymethoxy-21,26,27-trinor-5α-cholest-23-yn-22-ols (VI and VII) which