5717-44-2

Basic information

• Product Name: 2-Methyl-4-phenyl-2,3-pentadienoic acid ethyl ester
• Synonyms: 2-Methyl-4-phenyl-2,3-pentadienoic acid ethyl ester
• CAS NO: 5717-44-2
• Molecular Formula: C₁₄H₁₆O₂
• Molecular Weight: 216.28
• Mol File: 5717-44-2.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Methyl-4-phenyl-2,3-pentadienoic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Methyl-4-phenyl-2,3-pentadienoic acid ethyl ester(5717-44-2)
• EPA Substance Registry System: 2-Methyl-4-phenyl-2,3-pentadienoic acid ethyl ester(5717-44-2)

Safety Data

• Hazardous Substances Data: 5717-44-2(Hazardous Substances Data)

Upstream product

• 25145-43-1 2-phenylpropionyl chloride 
• 3699-66-9 ethyl 2-diethoxyphosphorylpropionate 
• 3156-07-8 methyl phenyl ketene 
• 21382-82-1 (carbethoxyethylidene)triphenylphosphorane 
• 15849-86-2 methyl(phenyl)chlorophosphine 
• 535-11-5 Ethyl 2-bromopropionate 
• 4371-02-2 2-methyl-2-phenylmalonic acid 
• 30018-16-7 (1-ethoxycarbonylethyl)triphenylphosphonium bromide 

Downstream Products

• 36858-88-5 S-(+)-2-Methyl-4-phenyl-pentadien-(2,3)-carbonsaeure 
• 57585-21-4 4-phenylpenta-2,3-dienoic acid 
• 36858-88-5 α,γ-Dimethyl-γ-phenyl-allencarbonsaeure 
• 36858-88-5 R-(-)-2-Methyl-4-phenyl-pentadien-(2,3)-carbonsaeure 
• 1089678-79-4 4-allyl-5-methyl-7-phenyl-1,5,6-octatrien-4-ol 
• 1006376-89-1 4-fluoro-3,5-dimethyl-5-phenyl-2(5H)-furanone 

Relevant articles and documents

Study on the selectivity in the electrophilic monofluorination of 2,3-allenoates with Selectfluor: An efficient synthesis of 4-fluoro-2(5H)-furanones and 3-fluoro-4-oxo-2(E)-alkenoates

Different from the reaction of 2,3-allenoic acids with Selectfluor, 4-fluoro-2(5H)-furanones and (E)-3-fluoro-4-oxo-2-alkenoates were highly selectively generated from 2,4-disubstituted 2,3-allenoates with Selectfluor under different conditions in moderate yields. The reaction of 2, 4, 4-trisubstituted 2,3-allenoates afforded the corresponding 4-fluoro-2(5H)-furanones highly selectively with up to 95% yield under different conditions. The scope of the substrates has been carefully explored. Due to the more readily availability of 2,3-allenoates as compared to 2,3-allenoic acids, new 4-fluoro-2(5H)furanones were prepared. Based on the isolation and characterization of the minor fluorohydroxylation product E-5m, a mechanism has been proposed. The Royal Society of Chemistry 2010.