57181-82-5

Basic information

• Product Name: Benzene, (1-bromo-2-methylpropyl)-
• CAS NO: 57181-82-5
• Molecular Formula: C10H13Br
• Molecular Weight: 213.117
• Mol File: 57181-82-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzene, (1-bromo-2-methylpropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1-bromo-2-methylpropyl)-(57181-82-5)
• EPA Substance Registry System: Benzene, (1-bromo-2-methylpropyl)-(57181-82-5)

Safety Data

• Hazardous Substances Data: 57181-82-5(Hazardous Substances Data)

Upstream product

• 3145-76-4 (2-methylcyclopropyl)benzene 
• 611-69-8 rac-2-methyl-1-phenylpropan-1-ol 
• 10035-10-6 hydrogen bromide 
• 100-52-7 benzaldehyde 
• 538-93-2 1-phenyl-2-methylpropane 

Downstream Products

• 768-49-0 (2-methyl-1-propenyl)-benzene 
• 110047-87-5 meso-2,5-Dimethyl-3,4-diphenylhexan 
• 1333501-16-8 2,2,6,6-tetramethyl-1-(2-methyl-1-phenylpropoxy)piperidine 
• 611-70-1 phenyl isopropyl ketone 
• 58040-60-1 (4-methylpent-1-yne-1,3-diyl)dibenzene 
• 412271-30-8 N-(4-methoxyphenyl)-N-(2-methyl-1-phenylpropyl)amine 
• 1333501-17-9 C₄₆H₆₀N₄O₇S₂ 
• 1333501-36-2 2,2,6,6-tetramethyl-1-(2-methyl-1-phenylpropoxy)piperidine-4-ylamine 
• 1333501-35-1 2,2,6,6-tetramethyl-1-(2-methyl-1-phenylpropoxy)piperidine-4-one 

Relevant articles and documents

In Situ Generated Gold Nanoparticles on Active Carbon as Reusable Highly Efficient Catalysts for a Csp3 ?Csp3 Stille Coupling

Gold nanoparticle catalysts are important in many industrial production processes. Nevertheless, for traditional Csp2-Csp2 cross-coupling reactions they have been rarely used and Pd catalysts usually give a superior performance. Herein we report that in situ formed gold metal nanoparticles are highly active catalysts for the cross coupling of allylstannanes and activated alkylbromides to form Csp3-Csp3 bonds. Turnover numbers up to 29 000 could be achieved in the presence of active carbon as solid support, which allowed for convenient catalyst recovery and reuse. The present study is a rare case where a gold metal catalyst is superior to Pd catalysts in a cross-coupling reaction of an organic halide and an organometallic reagent.

PROCESS FOR PREPARING ARYL KETONE

A process for preparing aryl ketones is disclosed. The process includes photo-oxidizing a compound of formula (V), (VI), (VII) or (VIII): in the presence of an oxidative system comprising at least one bromide compound to form aryl ketones. X1, X2, R1, R2, R3, L1, L2, L3, L4, t, n, m and p have the meanings as described in the specification and claims.

Direct and selective benzylic oxidation of alkylarenes via C-H abstraction using alkali metal bromides

A direct benzylic oxidation of alkylarenes via C-H bond abstraction was developed using alkali metal bromides and oxidants under mild conditions. This reaction proceeded with excellent selectivity by thermal oxidation or photooxidation to provide a broad range of carbonyl compounds containing electron-deficient aryl carbonyl compounds in high yields.