57197-12-3

Basic information

• Product Name: 2,5-Cyclohexadien-1-one, 4,4-dimethoxy-2,6-dimethyl-
• CAS NO: 57197-12-3
• Molecular Formula: C10H14O3
• Molecular Weight: 182.219
• Mol File: 57197-12-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2,5-Cyclohexadien-1-one, 4,4-dimethoxy-2,6-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-Cyclohexadien-1-one, 4,4-dimethoxy-2,6-dimethyl-(57197-12-3)
• EPA Substance Registry System: 2,5-Cyclohexadien-1-one, 4,4-dimethoxy-2,6-dimethyl-(57197-12-3)

Safety Data

• Hazardous Substances Data: 57197-12-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 576-26-1 2.6-dimethylphenol 
• 654-42-2 1,4-dihydroxy-2,6-dimethylbenzene 
• 2431-91-6 4-methoxy-2,6-dimethylphenol 

Downstream Products

• 1027594-94-0 4,4-Dimethoxy-2,6-dimethyl-1-((R)-toluene-4-sulfinylmethyl)-cyclohexa-2,5-dienol 
• 127718-78-9 2-(2,2-Dimethoxy-4,6-dimethyl-5-oxo-cyclohex-3-enyl)-malononitrile 

Relevant articles and documents

Bromide-assisted oxidation of substituted phenols with hydrogen peroxide to the corresponding p-quinol and p-quinol ethers over WO4 2--exchanged layered double hydroxides

A simple and efficient one-pot synthesis of p-quinols and their ethers occurs over tungstate-exchanged layered double hydroxides (WO4 2--LDHs), which catalyze the bromide-assisted oxidation of substituted phenols to the corresponding 4-alkoxy- and 4-hydroxycyclohexa-2,5- dienones in high yields (see scheme).

π-Facial Diastereoselection in Diels-Alder Reactions of (R)-4-[(p-Tolylsulfinyl)methyl]quinols

Diels-Alder reactions of a range of (R)-4-hydroxy-4-[(p-tolylsulfinyl)methyl]-2,5-cyclohexadienones with cyclopentadiene and 1,3-pentadiene proceed in a total π-facial diastereoselective manner from the C-4 OH side. Ab initio calculations at the RHF/6-31G