57204-88-3

Basic information

• Product Name: Benzenemethanol, a-ethylidene-, lithium salt
• CAS NO: 57204-88-3
• Molecular Formula: C9H10O.Li
• Molecular Weight: 140.111
• Mol File: 57204-88-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-ethylidene-, lithium salt(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-ethylidene-, lithium salt(57204-88-3)
• EPA Substance Registry System: Benzenemethanol, a-ethylidene-, lithium salt(57204-88-3)

Safety Data

• Hazardous Substances Data: 57204-88-3(Hazardous Substances Data)

Upstream product

• 93-55-0 1-phenyl-propan-1-one 
• 591-51-5 phenyllithium 
• 137604-19-4 Lithium; 1-phenyl-prop-2-en-1-olate 

Downstream Products

• 93617-69-7 2-(1-Methyl-2-oxo-2-phenyl-ethyl)-2H-pyridine-1-carboxylic acid phenyl ester 
• 93617-68-6 4-(1-Methyl-2-oxo-2-phenyl-ethyl)-4H-pyridine-1-carboxylic acid phenyl ester 
• 52776-41-7 2,3-dimethyl-1-phenyl-2-butene-1-one 
• 34733-55-6 2,3-dimethyl-1,4-diphenyl-butane-1,4-dione 
• 78706-73-7 2,3-dimethyl-3-nitro-1-phenyl-1-butanone 
• 14195-15-4 α-(p-methylbenzenesulfonyl)propiophenone 
• 1197189-53-9 (Z)-dimethyl(2-methylallyl)(1-phenylprop-1-enyloxy)silane 
• 1197189-55-1 (Z)-(2-(benzyloxymethyl)allyl)dimethyl(1-phenylprop-1-enyloxy)silane 
• 61878-73-7 3-hydroxy-2-methyl-1,3-diphenyl-propan-1-one 
• 73739-31-8 (3SR,2SR)-1-phenyl-2-methyl-3-hydroxy-pentan-1-one 
• 73739-31-8 (3SR,2RS)-1-phenyl-2-methyl-3-hydroxy-pentan-1-one 
• 71908-02-6 (2SR,3RS)-3-hydroxy-2-methyl-1,3-diphenylpropan-1-one 
• 71908-03-7 (2SR,3RS)-2-methyl-1,3-diphenyl-3-hydroxypropan-1-one 
• 14897-67-7 2-nitropropiophenone 

Relevant articles and documents

Highly functionalized and potent antiviral cyclopentane derivatives formed by a tandem process consisting of organometallic, transition-metal-catalyzed, and radical reaction steps

A simple modular tandem approach to multiply substituted cyclopentane derivatives is reported, which succeeds by joining organometallic addition, conjugate addition, radical cyclization, and oxygenation steps. The key steps enabling this tandem process are the thus far rarely used isomerization of allylic alkoxides to enolates and single-electron transfer to merge the organometallic step with the radical and oxygenation chemistry. This controlled lineup of multiple electronically contrasting reactive intermediates provides versatile access to highly functionalized cyclopentane derivatives from very simple and readily available commodity precursors. The antiviral activity of the synthesized compounds was screened and a number of compounds showed potent activity against hepatitisC and dengue viruses.