57260-91-0

Basic information

• Product Name: Cyclohexane, 1-(methylsulfinyl)-1-(methylthio)-
• CAS NO: 57260-91-0
• Molecular Formula: C8H16OS2
• Molecular Weight: 192.346
• Mol File: 57260-91-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclohexane, 1-(methylsulfinyl)-1-(methylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, 1-(methylsulfinyl)-1-(methylthio)-(57260-91-0)
• EPA Substance Registry System: Cyclohexane, 1-(methylsulfinyl)-1-(methylthio)-(57260-91-0)

Safety Data

• Hazardous Substances Data: 57260-91-0(Hazardous Substances Data)

Upstream product

• 4479-55-4 cyclohexanone-dimethyldithioacetal 
• 24293-28-5 1,5-bis(p-toluenesulfonyloxy)pentane 
• 33577-16-1 methyl methylsulfinylmethyl sulfide 
• 111-24-0 1,5-dibromo-pentane 

Downstream Products

• 58898-01-4 2-(1-Methylsulfanyl-cyclohexanesulfinyl)-1,1-diphenyl-ethanol 
• 58898-10-5 1-(Dodecane-1-sulfinyl)-1-methylsulfanyl-cyclohexane 
• 58898-06-9 2-Phenyl-2-phenylamino-ethanethiol 
• 58898-02-5 [2-(1-Methylsulfanyl-cyclohexanesulfinyl)-1-phenyl-ethyl]-phenyl-amine 
• 1670-47-9 1,1-diethoxycyclohexane 
• 624-92-0 Dimethyldisulphide 
• 108-94-1 cyclohexanone 

Relevant articles and documents

A Versatile Synthesis of Four-, Five-, and Six-membered Cyclic Ketones Using Methyl Methylthiomethyl Sulfoxide

Cyclization of 1,n-dihaloalkanes with methyl methylthiomethyl sulfoxide in the presence of a base (n-BuLi or KH) gave three-, four-, five-, and six-membered 1-methylsulfinyl-1-methylthiocycloalkanes.These cyclization products were easily converted to the corresponding ketones by acid hydrolysis except 1-methylsulfinyl-1-methylthiocyclopropane which afforded a complicated mixture.The combination of the cyclization with the acidhydrolysis thus provides a new method for synthesizing four-, five-, and six-membered cycloalkanones.Several representative preparations, such as those of substituted cyclobutanones, 3-cyclopentanone, and tetrahydro-4-pyrone are described.