57261-91-3

Basic information

• Product Name: Cyclohexanamine, N-(2-ethylbutylidene)-
• CAS NO: 57261-91-3
• Molecular Formula: C12H23N
• Molecular Weight: 181.321
• Mol File: 57261-91-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Cyclohexanamine, N-(2-ethylbutylidene)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanamine, N-(2-ethylbutylidene)-(57261-91-3)
• EPA Substance Registry System: Cyclohexanamine, N-(2-ethylbutylidene)-(57261-91-3)

Safety Data

• Hazardous Substances Data: 57261-91-3(Hazardous Substances Data)

Upstream product

• 931-53-3 Cyclohexyl isocyanide 
• 109-66-0 pentane 
• 97-96-1 2-Ethylbutyraldehyde 
• 108-91-8 cyclohexylamine 

Downstream Products

• 30857-49-9 cyclohexyl-(2,2-diethyl-hexylidene)-amine 
• 30857-64-8 Diethyl-2,2-phenyl-3-propanal-cyclohexylimin 
• 30857-74-0 Diaethyl-2,2-phenyl-3-propanal 
• 26254-89-7 2,2-diethylbutyraldehyde 
• 30857-47-7 cyclohexyl-(2,2-diethyl-pent-4-enylidene)-amine 
• 71201-99-5 2,2-diethylpent-4-enal 

Relevant articles and documents

Aminomethylation reaction of Ortho -pyridyl C-H bonds catalyzed by group 3 metal triamido complexes

Tris[N,N-bis(trimethylsilyl)amido] complexes of group 3 metals, especially yttrium and gadolinium, served as catalysts for ortho-C-H bond addition of pyridine derivatives and N-heteroaromatics into the C=N double bond of nonactivated imines to afford the corresponding aminomethylated products. Addition of catalytic amounts of secondary amines, such as dibenzylamine, dramatically improved the catalytic activity through the formation of a mixed ligated complex such as [(Me3Si)2N]2Y(NBn2)(THF) (4). Furthermore, kinetic studies using the isolated complex 4 provided a plausible reaction mechanism by which coordination of two pyridine derivatives afforded a penta-coordinated species as a key step.