57266-90-7Relevant articles and documents
Iridium-Catalyzed Enantioselective Hydrogenation of Vinylsilanes
Wang, Aie,Bernasconi, Maurizio,Pfaltz, Andreas
, p. 2523 - 2529 (2017/08/16)
We have screened a diverse array of iridium complexes derived from chiral N,P ligands as catalysts for the asymmetric hydrogenation of vinylsilanes, a transformation for which generally applicable catalysts were lacking. Several catalysts emerged from thi
The efficient stereoselective synthesis of Z-vinylsilanes through the Suzuki-Miyaura coupling of Z-(α-silylvinyl)borinates
Soderquist, John A.,Leon, Gisela
, p. 3989 - 3990 (2007/10/03)
Air-stable Z-(α-silylvinyl)borinates (2), easily prepared in a hydroboration-oxidation sequence from I provide a particularly effective route to Z-vinylsilanes (3, 59-97%) through Suzuki-Miyaura coupling.