57355-72-3Relevant articles and documents
Photochemical synthesis of 3-alkynals from 1-alkynoxy-9,10-anthraquinones
Blankespoor, Ronald L.,Boldenow, Peter J.,Hansen, Eric C.,Kallemeyn, Jeffrey M.,Lohse, Andrew G.,Rubush, David M.,Vrieze, Derek
, p. 3933 - 3935 (2009)
(Chemical Equation Presented) Photolysis of 1-(3-alkynoxy)-9,10- anthraquinones in deoxygenated methanol leads to moderate yields (35-45%) of 3-alkynals along with the unexpected formation of diacetals. Reaction of these 3-alkynals with Grignard and Witti