57457-95-1

Basic information

• Product Name: trans carveol 3,5-dinitrobenzoate
• Synonyms: trans carveol 3,5-dinitrobenzoate
• CAS NO: 57457-95-1
• Molecular Weight: 346.34
• Mol File: 57457-95-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: trans carveol 3,5-dinitrobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: trans carveol 3,5-dinitrobenzoate(57457-95-1)
• EPA Substance Registry System: trans carveol 3,5-dinitrobenzoate(57457-95-1)

Safety Data

• Hazardous Substances Data: 57457-95-1(Hazardous Substances Data)

Upstream product

• 1134-95-8 2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-yl acetate 
• 73524-01-3 trans-carveol benzoate 
• 79055-08-6 (+/-)-O-(4-Nitro-benzoyl)-trans-carveol 
• 80-56-8 Pinene 
• 1197-07-5 (+/-)-trans-carveol 
• 99-33-2 3,5-dinitrobenoyl chloride 
• 57429-67-1 3,5-dinitrobenzoate ester of (+)-trans-carveol 
• 6485-40-1 (R)-Carvone 
• 99-48-9 (4R,6R)-carveol 
• 57429-67-1 (-)-cis-carveol 3,5-dinitrobenzoate 
• 57429-67-1 (+)-cis-carveol 3,5-dinitrobenzoate 
• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 42477-94-1 trans-(S)-(-)-limoneneoxide 
• 79307-11-2 Imidazole-1-carbothioic acid O-((1S,4R,6S)-4-isopropenyl-1-methyl-7-oxa-bicyclo[4.1.0]hept-2-yl) ester 

Downstream Products

• 57429-67-1 (+/-)-trans-carveol 3,5-dinitrobenzoate 
• 57429-67-1 (+/-)-O-(3.5-dinitro-benzoyl)-cis-carveol 
• 1197-06-4 cis-2-methyl-5-(1-methylethenyl)-2-cyclohexen-1-ol 
• 1197-07-5 (+/-)-trans-carveol 
• 79055-08-6 (+/-)-O-(4-Nitro-benzoyl)-trans-carveol 
• 7632-16-8 (2S,4S)-carveol 

Relevant articles and documents

Radical-induced Ring Opening of Epoxides. A Convenient Alternative to the Wharton Rearrangement

Tri-n-butyltin hydride reduction of an αβ-epoxy-O-thiocarbonylimidazolide derivative of an alcohol leads via oxiran ring-opening to the formation of an allylic alkoxyl radical.By a suitable choice of experimental conditions, this radical can either be quenched by hydrogen-atom transfer from the stannane or allowed to undergo further rearrangement.

Stereochemical Studies on the Nucleophilic Substitution in the Reaction of Allylic Phosphates with Organoaluminum Reagents

The reaction of cis- or trans-5-isopropenyl-2-methyl-2-cyclohexenyl diethyl phosphate (1) with Me2AlX (X= OPh, SPh, NHPh) in hexane results in substitution of the -O-PO(OEt)2 group with X under predominant inversion.In contrast, treatment of cis- or trans-1 with trialkylaluminum produces predominantly the allyl-nonallyl coupling products of the same (thermodynamically more stable) configuration.Similar alkylation of endo- and exo-2-acetoxynorcarane gave endo-2-methylnorcarane, exclusively.