5756-03-6

Basic information

• Product Name: diphenyl propylamino phosphate
• Synonyms: diphenyl propylamino phosphate
• CAS NO: 5756-03-6
• Molecular Weight: 291.287
• Mol File: 5756-03-6.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: diphenyl propylamino phosphate(CAS DataBase Reference)
• NIST Chemistry Reference: diphenyl propylamino phosphate(5756-03-6)
• EPA Substance Registry System: diphenyl propylamino phosphate(5756-03-6)

Safety Data

• Hazardous Substances Data: 5756-03-6(Hazardous Substances Data)

Upstream product

• 2524-64-3 chlorophosphoric acid diphenyl ester 
• 107-10-8 propylamine 
• 26386-88-9 diphenyl phosphoryl azide 
• 4712-55-4 diphenyl hydrogen phosphite 
• 53931-67-2 propyl-amidophosphoryl chloride 
• 108-95-2 phenol 

Downstream Products

• 838-85-7 diphenyl hydrogen phosphate 
• 107-10-8 propylamine 

Relevant articles and documents

Substitution of diarylphosphoryl azides with aliphatic amines catalyzed by simple rare-earth metal salts: Efficient and novel preparation of phosphoryl amides

A novel and high efficient protocol was disclosed herein for the rare-earth metal salt-catalyzed substitution of phosphoryl azides with amines. In this homogeneous catalysis system, different diarylphosphoryl azides and aliphatic and aromatic amines were

Zinc-catalyzed transformation of diarylphosphoryl azides to diarylphosphate esters and amides

We have developed a facile and efficient procedure for the synthesis of diarylphosphate esters and amides. Using Zn(acac)2 as the catalyst, the reaction of diarylphosphoryl azides with aliphatic alcohols and phenols through an unusual P?N bond cleavage provided a number of diarylphosphate esters in good yields (22 examples, up to 94%). Additionally, various diarylphosphate amides were obtained from the corresponding amines in excellent yields as well (8 examples, up to 96%).

O -Phthalaldehyde catalyzed hydrolysis of organophosphinic amides and other P(O)-NH containing compounds

Over 50 years ago, Jencks and Gilchrist showed that formaldehyde catalyses the hydrolysis of phosphoramidate through electrophilic activation, induced by covalent attachment to its nitrogen atom. Given our interest in the use of aldehydes as catalysts, this work was revisited to identify a superior catalyst, o-phthalaldehyde, which facilitates hydrolyses of various organophosphorus compounds bearing P(O)-NH subunits under mild conditions. Interestingly, chemoselective hydrolysis of the P(O)-N bonds could be accomplished in the presence of P(O)-OR bonds.