57585-10-1Relevant articles and documents
Synthesis of Allenyl Esters by Horner-Wadsworth-Emmons Reactions of Ketenes Mediated by Isopropylmagnesium Bromide
Sano, Shigeki,Matsumoto, Tomoya,Yano, Teppei,Toguchi, Munehisa,Nakao, Michiyasu
supporting information, p. 2135 - 2138 (2015/09/15)
The synthesis of conjugated allenyl esters (tri-substituted allenes) was achieved by magnesium(II)-mediated Horner-Wadsworth-Emmons reaction of methyl bis(2,2,2-trifluoroethyl)phosphonoacetate with disubstituted ketenes. In addition, a novel access to α-fluorinated allenyl carboxamides (tetrasubstituted allenes) is presented.
Enantioselective preparation of allenecarboxylates by asymmetric Horner-Wadsworth-Emmons reaction
Tanaka, Kiyoshi,Otsubo, Kenji,Fuji, Kaoru
, p. 3735 - 3738 (2007/10/03)
Optically active 4,4-disubstituted conjugated allenecarboxylates were enantioselectively prepared via C=C bond formation through an asymmetric Horner-Wadsworth-Emmons reaction with an optically active phosphonoacetate reagent.